Pregled bibliografske jedinice broj: 395967
Electrochemical synthesis of polyaniline from aniline/cyclodextrin solutions
Electrochemical synthesis of polyaniline from aniline/cyclodextrin solutions // Journal of electroanalytical chemistry (1992), 643 (2010), 1-2; 46-51 doi:10.1016/j.jelechem.2010.03.010 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 395967 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Electrochemical synthesis of polyaniline from aniline/cyclodextrin solutions
Autori
Kraljić Roković, Marijana ; Perši, Bojana ; Mandić, Zoran
Izvornik
Journal of electroanalytical chemistry (1992) (1572-6657) 643
(2010), 1-2;
46-51
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
polymers ; semiconductors ; electrochemical techniques
Sažetak
The influence of cyclodextrin on the electrochemical synthesis and properties of polyaniline was determined. The oxidation of aniline and the polymer growth were investigated by cyclic voltammetry and electrochemical quartz crystal microbalance in the presence of either b-cylodextrin or sulfated b-cylodextrin. Measurements were carried out using Pt working electrode and 10-2 mol dm-3 aniline in 1 mol dm-3 NaClO4 supporting electrolyte solution. Various amounts of both cyclodextrins were used in order to obtain aniline : cyclodextrin molar ratios from 1:0 - 1:50. The obtained results show that the addition of cyclodextrins decreases aniline oxidation current as well as overall polymer growth rate. The different effect was obtained in the presence of b-cylodextrin compared to sulfated b-cylodextrin. Structural, electrochemical and morphological properties of resulting polyanilines are also influenced by different type of cyclodextrins.
Izvorni jezik
Engleski
Znanstvena područja
Kemija, Kemijsko inženjerstvo
POVEZANOST RADA
Projekti:
MZOS-098-0982904-2905 - Elektroaktivni filmovi za ekološki prihvatljivu konverziju i pohranu energije (Horvat-Radošević, Višnja, MZOS ) ( CroRIS)
MZOS-125-1252973-2576 - Temeljna i primijenjena istraživanja vodljivih polimera (Mandić, Zoran, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus