Naslov
Paterno-Buechi reaction between aromatic carbonyl compounds and 1-(3-furyl)alkanols

Autori
D'Auria, Maurizio ; Emanuele, Lucia ; Racioppi, Rocco ; Valente, Anna

Izvornik
Photochemical & photobiological sciences (1474-905X) 7 (2008), 1; 98-103

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
chiral allylic alcohols; 2-furylmethanol derivatives; kinetic resolution; furan-derivatives; stereoselectivity; 2-furylcarbinols; benzophenone

Sažetak
The photochemical reaction between aromatic carbonyl compounds and 3-furylmethanol derivatives occurs with high regioselectivity. In most of the experiments formation of oxetanes occurs at the hydroxyalkylated double bond. With chiral 1-(3-furyl) alkanols the reaction occurs with good-high stereoselectivity. In the case of 1-(3-furyl)-benzyl alcohol the stereoselectivity can be explained on the basis of the conformers of the reagent, assuming the formation of a complex between the carbonyl compound and the hydroxyl group.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA