Pregled bibliografske jedinice broj: 386272
Synthesis and Chemistry of 2, 8-Disubstituted Noradamantanes
Synthesis and Chemistry of 2, 8-Disubstituted Noradamantanes // Journal of organic chemistry, 49 (1984), 7; 1182-1185 doi:10.1021/jo00181a007 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 386272 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Synthesis and Chemistry of 2, 8-Disubstituted Noradamantanes
Autori
Majerski, Zdenko ; Hameršak, Zdenko
Izvornik
Journal of organic chemistry (0022-3263) 49
(1984), 7;
1182-1185
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
noradamantanes ; synthesis
Sažetak
4, 5-exo-Epoxybrendane (3) rearranged readily with sulfuric acid in acetone, and with boron trifluoride etherate in acetic acid, yielding, upon a hydrolytic workup, 86% of 2-exo-8-exo-noradamantanediol and 93% of 8-exoacetoxy- 2-ero-noradamantano1, respectively. Starting epoxide 3 was prepared in 60% overall yield from readily available 4-brendanone. Consequently, the acid solvolysis of 3 provides a convenient, general entry to the noradamantane system functionalized at carbons 2 and 8.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
