Pregled bibliografske jedinice broj: 381456
Preparation of an enantiomerically pure, highly porous metalloorganic crystal
Preparation of an enantiomerically pure, highly porous metalloorganic crystal // Inorganica Chimica Acta, 357 (2004), 15; 4610-4613 doi:10.1016/j.ica.2004.07.024 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 381456 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Preparation of an enantiomerically pure, highly porous metalloorganic crystal
Autori
Kobetić, Renata ; Stevens, Edwin ; Piotrowiak, Piotr
Izvornik
Inorganica Chimica Acta (0020-1693) 357
(2004), 15;
4610-4613
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Chiral crystal; Spirane ligands
Sažetak
We report the synthesis and the structure determination of tris-(4, 5-diazo-spiro-bifluorene)ruthenium(II) chloride, a chiral building block whose racemic mixture solution spontaneously resolves and forms two crystalline, enantiomerically pure, porous networks composed exclusively of the lambda and delta atropisomera. The extended chiral channels are occupied by water molecules (approximately 20% by weight) and the chloride counter-ions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
