Pregled bibliografske jedinice broj: 381451
Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines
Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines // Supramolecular Chemistry, 20 (2008), 4; 369-377 doi:10.1080/10610270701268807 (međunarodna recenzija, članak, znanstveni)
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Naslov
Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines
Autori
Kobetić, Renata ; Sunko, Dionis
Izvornik
Supramolecular Chemistry (1061-0278) 20
(2008), 4;
369-377
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Hydrolysyis; Cyclopentenyl-alkyl-nicotinates; Cyclodextrines; Micelles; Selectivity
Sažetak
The formation, via superstructures of a high selectivity was obtained through the ionic interaction, electronic charge-transfer interaction, hydrophobic interaction, and van der Waals interaction in the hydrolysis of iodide-2-( 3-cyclopentenyl)-ethyl-N-methyl-nicotinate, 12, and iodide-3-( 3-cyclopenthenyl)-propyl-N-methyl-nicotinate, 14, in micelles and cyclodextrins. Hydrolysis was accomplished in the aqueous solutions of  - and  - cyclodextrins (CD) and in the aqueous solutions of cetyltrimethylammonium bromide (CTAB). The choice of the leaving group (nicotinate) and the reaction medium influence the reaction rate and the composition of the formed products. Contrary to published data, the hydrolysis of iodide-2-( 3-cyclopenthenyl)-ethyl-N-methyl-nicotinate, 12, in the presence of  -CD yielded endo-2-norborneol.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Napomena
Projekt 2.03.01.00.012
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
