Pregled bibliografske jedinice broj: 376316
Inverse spinel structure in cobalt doped gahnite
Inverse spinel structure in cobalt doped gahnite // American mineralogist, 94 (2009), 5; 771-776 (međunarodna recenzija, članak, znanstveni)
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Naslov
Inverse spinel structure in cobalt doped gahnite
Autori
Popović, Jasminka ; Tkalčec, Emilija ; Gržeta, Biserka ; Kurajica, Stanislav ; Rakvin, Boris
Izvornik
American mineralogist (0003-004X) 94
(2009), 5;
771-776
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
gahnite; spinel structure; X-ray powder diffraction; Rietveld method
Sažetak
Powder ZnAl2O4 (gahnite) samples doped with 0-100 at% Co were obtained by a sol-gel technique. X-ray powder diffraction was used to characterize the samples. Gahnite samples were cubic with spinel-type structure, space group Fd-3m. Cobalt doping caused the nonuniform increase of unit-cell parameter. The structure of gahnite samples was refined by the Rietveld method. Location of Co2+ was performed by the EPR spectroscopy. Cobalt doping of gahnite induced the inverse spinel structure already for 4 at% Co, inversion parameter increased with Co2+ doping level. Metal-oxide distances in the (Al, Co)O6 octahedra dominantly influenced the unit-cell parameter of Co-doped gahnite.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija, Kemijsko inženjerstvo
POVEZANOST RADA
Projekti:
098-0982886-2893 - Dopirani optoelektronički i keramički nanomaterijali (Gržeta, Biserka, MZOS ) ( CroRIS)
098-0982915-2939 - Molekulska struktura i dinamika sustava s paramagnetskim česticama (Ilakovac-Kveder, Marina, MZOS ) ( CroRIS)
125-1252970-2981 - Keramički nanokompoziti dobiveni sol-gel postupkom (Kurajica, Stanislav, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Stanislav Kurajica
(autor)
Boris Rakvin
(autor)
Emilija Tkalčec-Čižmek
(autor)
Biserka Gržeta
(autor)
Jasminka Popović
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- INSPEC