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Pregled bibliografske jedinice broj: 376316

Inverse spinel structure in cobalt doped gahnite


Popović, Jasminka; Tkalčec, Emilija; Gržeta, Biserka; Kurajica, Stanislav; Rakvin, Boris
Inverse spinel structure in cobalt doped gahnite // American mineralogist, 94 (2009), 5; 771-776 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 376316 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Inverse spinel structure in cobalt doped gahnite

Autori
Popović, Jasminka ; Tkalčec, Emilija ; Gržeta, Biserka ; Kurajica, Stanislav ; Rakvin, Boris

Izvornik
American mineralogist (0003-004X) 94 (2009), 5; 771-776

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
gahnite; spinel structure; X-ray powder diffraction; Rietveld method

Sažetak
Powder ZnAl2O4 (gahnite) samples doped with 0-100 at% Co were obtained by a sol-gel technique. X-ray powder diffraction was used to characterize the samples. Gahnite samples were cubic with spinel-type structure, space group Fd-3m. Cobalt doping caused the nonuniform increase of unit-cell parameter. The structure of gahnite samples was refined by the Rietveld method. Location of Co2+ was performed by the EPR spectroscopy. Cobalt doping of gahnite induced the inverse spinel structure already for 4 at% Co, inversion parameter increased with Co2+ doping level. Metal-oxide distances in the (Al, Co)O6 octahedra dominantly influenced the unit-cell parameter of Co-doped gahnite.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija, Kemijsko inženjerstvo



POVEZANOST RADA


Projekti:
098-0982886-2893 - Dopirani optoelektronički i keramički nanomaterijali (Gržeta, Biserka, MZOS ) ( CroRIS)
098-0982915-2939 - Molekulska struktura i dinamika sustava s paramagnetskim česticama (Ilakovac-Kveder, Marina, MZOS ) ( CroRIS)
125-1252970-2981 - Keramički nanokompoziti dobiveni sol-gel postupkom (Kurajica, Stanislav, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb


Citiraj ovu publikaciju:

Popović, Jasminka; Tkalčec, Emilija; Gržeta, Biserka; Kurajica, Stanislav; Rakvin, Boris
Inverse spinel structure in cobalt doped gahnite // American mineralogist, 94 (2009), 5; 771-776 (međunarodna recenzija, članak, znanstveni)
Popović, J., Tkalčec, E., Gržeta, B., Kurajica, S. & Rakvin, B. (2009) Inverse spinel structure in cobalt doped gahnite. American mineralogist, 94 (5), 771-776.
@article{article, author = {Popovi\'{c}, Jasminka and Tkal\v{c}ec, Emilija and Gr\v{z}eta, Biserka and Kurajica, Stanislav and Rakvin, Boris}, year = {2009}, pages = {771-776}, keywords = {gahnite, spinel structure, X-ray powder diffraction, Rietveld method}, journal = {American mineralogist}, volume = {94}, number = {5}, issn = {0003-004X}, title = {Inverse spinel structure in cobalt doped gahnite}, keyword = {gahnite, spinel structure, X-ray powder diffraction, Rietveld method} }
@article{article, author = {Popovi\'{c}, Jasminka and Tkal\v{c}ec, Emilija and Gr\v{z}eta, Biserka and Kurajica, Stanislav and Rakvin, Boris}, year = {2009}, pages = {771-776}, keywords = {gahnite, spinel structure, X-ray powder diffraction, Rietveld method}, journal = {American mineralogist}, volume = {94}, number = {5}, issn = {0003-004X}, title = {Inverse spinel structure in cobalt doped gahnite}, keyword = {gahnite, spinel structure, X-ray powder diffraction, Rietveld method} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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