Pregled bibliografske jedinice broj: 363853
A theory of square-wave voltammetry of surface-active, electroinactive compounds
A theory of square-wave voltammetry of surface-active, electroinactive compounds // Electrochimica acta, 53 (2008), 27; 8045-8050 doi:10.1016/j.electacta.2008.06.010 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 363853 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
A theory of square-wave voltammetry of surface-active, electroinactive compounds
Autori
Jadreško, Dijana ; Lovrić, Milivoj
Izvornik
Electrochimica acta (0013-4686) 53
(2008), 27;
8045-8050
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Adsorption ; Surface-active substance ; Tensammetry ;
Sažetak
A potential-dependent adsorption of electroinactive species on the surface of working electrode is investigated theoretically for square-wave voltammetry (SWV). It is demonstrated that tensammetric peak originates from the difference in surface coverage during the forward and backward series of pulses of SWV signal. Linear dependence of SWV net peak current on SW frequency, as well as of SWV net peak potential on dimensionless bulk concentration of reactant and Frumkin coefficient is predicted by the model.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
