Pregled bibliografske jedinice broj: 36125
Synthesis and crystal and molecular structure of trans-[PtCl_2 (8-dqmp)_ 2] (8-dqmp = diethyl 8-quinolylmethylphosphonate
Synthesis and crystal and molecular structure of trans-[PtCl_2 (8-dqmp)_ 2] (8-dqmp = diethyl 8-quinolylmethylphosphonate // Croatica chemica acta, 72 (1999), 2-3; 531-539 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 36125 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Synthesis and crystal and molecular structure of trans-[PtCl_2 (8-dqmp)_ 2] (8-dqmp = diethyl 8-quinolylmethylphosphonate
Autori
Matijašić, Ivanka ; Bocelli, Gabrijele ; Rizzoli, Corado ; Tušek-Božić, Ljerka
Izvornik
Croatica chemica acta (0011-1643) 72
(1999), 2-3;
531-539
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
crystal structure; platinum(II) complex; diethyl quinolylmethylphosphonate
Sažetak
The complex trans-[PtCl_2 (8-dqmp)_ 2] has been synthezised and the molecular structure has been determined by a crystallographic study. The platinum atom has a slightly distorted trans square-planar configuration with Pt1 - N1 = 2.042(4) and Pt1 - Cl1 = 2.306(1) A. The dihedral angle between the Pt coordination plane and the mean plane of the 8-quinolylmethyl moiety is 65.1(1)^o. The complex reveals a very interesting feature: a relatively short methylene proton-platinum separation of 2.309(5)A forming approximately the axial positions around the central metal atom. Refinment was performed by least-squares methods to final R value of 3.02%.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Ljerka Tušek-Božić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- CA Search (Chemical Abstracts)
