Pregled bibliografske jedinice broj: 355519
Dimethylselenide as a Probe for Reactions of Halogenated Alkoxyl Radicals in Aqueous Solution. Degradation of Dichloro- and Dibromomethane
Dimethylselenide as a Probe for Reactions of Halogenated Alkoxyl Radicals in Aqueous Solution. Degradation of Dichloro- and Dibromomethane // The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 112 (2008), 26; 5908-5916 doi:10.1021/jp711894k (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 355519 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Dimethylselenide as a Probe for Reactions of Halogenated Alkoxyl Radicals in Aqueous Solution. Degradation of Dichloro- and Dibromomethane
Autori
Makogon, Oksana ; Flyunt, Roman ; Tobien, Thomas ; Naumov, Sergej ; Bonifačić, Marija
Izvornik
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (1089-5639) 112
(2008), 26;
5908-5916
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
radicals ; degradation
Sažetak
Using pulse radiolysis and steady-state gama-radiolysis techniques, it has been established, that in air-saturated aqueous solutions, peroxyl radicals derived from CH2Cl2 and CH2Br2 react with dimethyl selenide (Me2Se) to form HCO2H, CH2O, CO2, and CO as final products. Based on detailed product studies, mechanisms are proposed for te free-radical degradation.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2949 - Površinski aktivne tvari, procesi u otopinama i na međupovršinama (Dutour Sikirić, Maja, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Marija Bonifačić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
