Synthesis and structure of N-substituted (1-ferrocenylethyl)amine derivatives

Čakić Semenčić, Mojca; Dropučić, Maja; Barišić, Lidija; Molčanov, Krešimir; Rapić, Vladimir

doi:10.1007/s11224-006-9118-x

Pregled bibliografske jedinice broj: 324003

Synthesis and structure of N-substituted (1-ferrocenylethyl)amine derivatives

Čakić Semenčić, Mojca; Dropučić, Maja; Barišić, Lidija; Molčanov, Krešimir; Rapić, Vladimir

Synthesis and structure of N-substituted (1-ferrocenylethyl)amine derivatives // Structural Chemistry, 18 (2007), 3; 273-278 doi:10.1007/s11224-006-9118-x (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 324003 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Synthesis and structure of N-substituted (1-ferrocenylethyl)amine derivatives

Autori
Čakić Semenčić, Mojca ; Dropučić, Maja ; Barišić, Lidija ; Molčanov, Krešimir ; Rapić, Vladimir

Izvornik
Structural Chemistry (1040-0400) 18 (2007), 3; 273-278

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
ferrocene ; amine ; lithiation ; ethoxycarbonylation ; structure analysis

Sažetak
N-Acetyl-(1-ferrocenylethyl)amine (8) was synthesized by N-acylation of (1-ferrocenylethyl)amine (7) in 84% yield. Reaction of N-acetyl-[1-(1'-bromo-ferrocenyl)ethyl]amine (4) (which was prepared by multistep sequence starting from bromoferrocene) with n-BuLi/ ClCOOEt gave 77% of N-acetyl-N-ethoxycarbonyl-(1-ferrocenylethyl)amine (6) instead of the expected ethyl 1'-[1-(acetamido)ethyl]ferrocene-1-carboxylate (5). Both structures were undoubtedly confirmed by (HR)MS, spectroscopy and single crystal X-ray structure analysis.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
058-1191344-3122 - Metalocenski biokonjugati, heterocikli i makromolekule (Kovač, Veronika, MZOS ) ( CroRIS)

Ustanove:
Prehrambeno-biotehnološki fakultet, Zagreb

Profili:

Mojca Čakić (autor)