Pregled bibliografske jedinice broj: 322839
Synthesis and structural characterization of metallated bioconjugates: C-terminal labeling of amino acids with aminoferrocene
Synthesis and structural characterization of metallated bioconjugates: C-terminal labeling of amino acids with aminoferrocene // Journal of Organometallic Chemistry, 692 (2007), 20; 4209-4214 (međunarodna recenzija, članak, znanstveni)
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Naslov
Synthesis and structural characterization of metallated bioconjugates: C-terminal labeling of amino acids with aminoferrocene
Autori
Jios, Jorge L. ; Kirin, Srećko I. ; Buceta, Norma N. ; Weyhermüller, Thomas ; Della Vedova, Carlos O. ; Metzler-Nolte, Nils
Izvornik
Journal of Organometallic Chemistry (0022-328X) 692
(2007), 20;
4209-4214
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
amino acids; bioorganometallic chemistry; ferrocene; peptides; X-ray
Sažetak
Aminoferrocene, H2N– Fc, has been substituted to the C-terminus of six amino acids using the HBTU/HOBt coupling protocol. The synthesized bioconjugates Boc-Aaa-NH-Fc, Aaa = Gly (1), Leu (2), Phe (3), Val (4), Cys(Acm) (5), Tyr(tBu) (6) (Acm = acetamidomethyl, tBu = tert-butyl), have been characterized by 1H NMR, 13C NMR, EI-MS, EI-HRMS, UV and CD spectroscopies. In addition, a VT NMR study on 4 and the X-ray structure of 1 are presented.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
