Pregled bibliografske jedinice broj: 321052
Thermodynamics of the Association Reaction of RbBr in Binary Mixtures of 2-Butanol and Water from 288.15 to 308.15 K
Thermodynamics of the Association Reaction of RbBr in Binary Mixtures of 2-Butanol and Water from 288.15 to 308.15 K // Acta Chimica Slovenica, 55 (2008), 2; 308-314 (međunarodna recenzija, članak, znanstveni)
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Naslov
Thermodynamics of the Association Reaction of RbBr in Binary Mixtures of 2-Butanol and Water from 288.15 to 308.15 K
Autori
Sokol, Vesna ; Tomaš, Renato ; Tominić, Ivo
Izvornik
Acta Chimica Slovenica (1318-0207) 55
(2008), 2;
308-314
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
rubidium bromide; 2-butanol + water mixtures; association to ion-pairs; thermodynamic quantities
Sažetak
Molar conductivities of dilute solutions of rubidium bromide in binary mixtures of 2-butanol and water were measured in the temperature range from 288.15 to 308.15 K at 5 K intervals. The limiting molar conductivity (Lamda_o) and association constant (K_A) were determined by treating experimental data with the Lee-Wheaton conductivity equation. Thermodynamic quantities for the ion-association reaction were derived from the temperature dependence of K_A. The obtained results provide information on ion-ion and ion-solvent interactions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
011-0000000-3220 - Elektroliti u miješanim otapalima (Sokol, Vesna, MZOS ) ( CroRIS)
Ustanove:
Kemijsko-tehnološki fakultet, Split
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
