Pregled bibliografske jedinice broj: 317811
(1, 10-Phenanthroline-kappa^2N, N’ )bis(2, 2, 6, 6-tetramethylheptane-3, 5-dionato-kappa^2O, O’ )-nickel(II)
(1, 10-Phenanthroline-kappa^2N, N’ )bis(2, 2, 6, 6-tetramethylheptane-3, 5-dionato-kappa^2O, O’ )-nickel(II) // Acta crystallographica. Section E, Structure reports online, 64 (2008), 1; 230-231 doi:10.1107/S160053680706672X (međunarodna recenzija, članak, znanstveni)
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Naslov
(1, 10-Phenanthroline-kappa^2N, N’ )bis(2, 2, 6, 6-tetramethylheptane-3, 5-dionato-kappa^2O, O’ )-nickel(II)
Autori
Kaitner, Branko ; Mesarek, Krešo ; Meštrović, Ernest
Izvornik
Acta crystallographica. Section E, Structure reports online (1600-5368) 64
(2008), 1;
230-231
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
octahedral nickel(II) complex ; phenanthroline adduct ; metal beta-diketonate ; crystal structure
Sažetak
The title compound, [Ni(C_11H_19O_2)_2(C_12H_8N_2)], was obtained from the reaction of bis(2, 2, 6, 6-tetramethylheptane-3, 5-dionato)nickel(II), [Ni(dpm)], and 1, 10-phenanthroline (phen). The Ni^II ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
MZOS-119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Kaitner, Branko, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
Uključenost u ostale bibliografske baze podataka::
- Chemical Abstracts
