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Pregled bibliografske jedinice broj: 309865

EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination

Novosel, Nikolina; Žilić, Dijana; Pajić, Damir; Jurić, Marijana; Perić, Berislav; Zadro, Krešo; Rakvin, Boris; Planinić, Pavica
EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination // Solid state sciences, 10 (2008), 10; 1387-1394 doi:10.1016/j.solidstatesciences.2008.01.021 (međunarodna recenzija, članak, znanstveni)

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Naslov
EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination

Autori
Novosel, Nikolina ; Žilić, Dijana ; Pajić, Damir ; Jurić, Marijana ; Perić, Berislav ; Zadro, Krešo ; Rakvin, Boris ; Planinić, Pavica

Izvornik
Solid state sciences (1293-2558) 10 (2008), 10; 1387-1394

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
heterometallic complex; zero-field splitting; EPR; magnetization

Sažetak
Magnetic properties of single crystals of the heterometallic complex [Cu(bpy)3]2[Cr(C2O4)3]NO3 9H2O (bpy = 2, 2'-bipyridine)have been investigated. From the recorded EPR spectra, the spin-Hamiltonian parameters have been determined. The magnetization measurements have shown magnetic anisotropy at low temperatures, which has been analysed as a result of the zero-field splitting of the CrIII ion. By fitting the exactly derived magnetization expression to the measured magnetization data, the axial zero-field splitting parameter, D, has been calculated. Comparing to the EPR measurements, it has been confirmed that D can be determined from the measurements of the macroscopic magnetization on the single crystals.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA

Projekti:
098-0982904-2946 - Višenuklearni metalni sustavi: sinteza i svojstva (Perić, Berislav, MZOS ) ( CroRIS)
098-0982915-2939 - Molekulska struktura i dinamika sustava s paramagnetskim česticama (Ilakovac-Kveder, Marina, MZOS ) ( CroRIS)
119-1191458-1017 - Nanomagneti (Zadro, Krešo, MZOS ) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Damir Pajić (autor)

Avatar Url Nikolina Novosel (autor)

Avatar Url Boris Rakvin (autor)

Avatar Url Krešo Zadro (autor)

Avatar Url Berislav Perić (autor)

Avatar Url Pavica Planinić (autor)

Avatar Url Dijana Žilić (autor)

Avatar Url Marijana Jurić (autor)

Poveznice na cjeloviti tekst rada:

Pristup cjelovitom tekstu rada doi www.sciencedirect.com ac.els-cdn.com dx.doi.org

Citiraj ovu publikaciju:

Novosel, Nikolina; Žilić, Dijana; Pajić, Damir; Jurić, Marijana; Perić, Berislav; Zadro, Krešo; Rakvin, Boris; Planinić, Pavica
EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination // Solid state sciences, 10 (2008), 10; 1387-1394 doi:10.1016/j.solidstatesciences.2008.01.021 (međunarodna recenzija, članak, znanstveni)
Novosel, N., Žilić, D., Pajić, D., Jurić, M., Perić, B., Zadro, K., Rakvin, B. & Planinić, P. (2008) EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination. Solid state sciences, 10 (10), 1387-1394 doi:10.1016/j.solidstatesciences.2008.01.021.
@article{article, author = {Novosel, Nikolina and \v{Z}ili\'{c}, Dijana and Paji\'{c}, Damir and Juri\'{c}, Marijana and Peri\'{c}, Berislav and Zadro, Kre\v{s}o and Rakvin, Boris and Planini\'{c}, Pavica}, year = {2008}, pages = {1387-1394}, DOI = {10.1016/j.solidstatesciences.2008.01.021}, keywords = {heterometallic complex, zero-field splitting, EPR, magnetization}, journal = {Solid state sciences}, doi = {10.1016/j.solidstatesciences.2008.01.021}, volume = {10}, number = {10}, issn = {1293-2558}, title = {EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination}, keyword = {heterometallic complex, zero-field splitting, EPR, magnetization} }
@article{article, author = {Novosel, Nikolina and \v{Z}ili\'{c}, Dijana and Paji\'{c}, Damir and Juri\'{c}, Marijana and Peri\'{c}, Berislav and Zadro, Kre\v{s}o and Rakvin, Boris and Planini\'{c}, Pavica}, year = {2008}, pages = {1387-1394}, DOI = {10.1016/j.solidstatesciences.2008.01.021}, keywords = {heterometallic complex, zero-field splitting, EPR, magnetization}, journal = {Solid state sciences}, doi = {10.1016/j.solidstatesciences.2008.01.021}, volume = {10}, number = {10}, issn = {1293-2558}, title = {EPR and magnetization studies on single crystals of a heterometallic (Cu|| and Cr|||) complex: zero-field splitting determination}, keyword = {heterometallic complex, zero-field splitting, EPR, magnetization} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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