Naslov
Effect of Corrosion on the Isoelectric Point of Stainless Steel

Autori
Kallay, Nikola ; Kovačević, Davor ; Dedić, Iris ; Tomašić, Vlasta

Izvornik
Corrosion (NACE) (0010-9312) 50 (1994), 8; 598-602

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
adhesion method; corrosion; electrokinetics; hematite; isoelectric point; lepidocrocite; magnetite; oxides; pH; sodium chloride; stainless steel; temperature; type 316L stainless steel

Sažetak
The recently developed adhesion method for determining the isoelectric points (IEP) of conductive metal surfaces was applied in studying the corrosion processes of stainless steel (SS). This techique allowed for characterization of the charge on the metal oxide surface as a function of pH. The magnitude of IEP was found to correlate with the structure of the oxide layer. The exposure of SS to air at 1.000 oC reduced the original pHIEP from 4.15 to 2.8 as a result of the presence of mahnetite. Treatment at lower temperatures yielded a significant portion of hematite in the oxide layer and pHIEP shifted to 3.3. The corrosion of SS in aqueous sodium chloride (NaCl) solution at room temperature, as examined by the proposed electrokinetic method, resulted in the formation of magnetite in the early stage of the process, while hematite and/or lepidocrocite was detected as final product.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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