Pregled bibliografske jedinice broj: 292562
Polymer-dimer distribution in the electrochemical synthesis of polyaniline
Polymer-dimer distribution in the electrochemical synthesis of polyaniline // Electrochimica acta, 40 (1995), 11; 1681-1688 doi:10.1016/0013-4686(95)00086-T (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 292562 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Polymer-dimer distribution in the electrochemical synthesis of polyaniline
Autori
Duić, Ljerka ; Mandić, Zoran ; Kovač, Spomenka
Izvornik
Electrochimica acta (0013-4686) 40
(1995), 11;
1681-1688
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
polyaniline ; 4-aminodiphenylamine ; electrooxidation ; electropolymerization
Sažetak
The distribution of major products associated with the process of polyaniline (PANI) synthesis is discussed. On the basis of the results obtained in the cyclic voltammetry and constant potential synthesis the dependence of that distribution upon monomer concetration, switching potential, potential of synthesis are discussed, the corresponding reaction scheme is given and terms for the reaction rates derived. The conditions governing the polymer-dimer distribution are formulated. The origin of the middle peak, appearing during PANI synthesis, is discussed in the light of the specific experimental conditions, and species corresponding to it are identified. The reaction scheme for the hydrolisis pathway of dimer is confirmed.
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
POVEZANOST RADA
Projekti:
0125010
Ustanove:
Prehrambeno-tehnološki fakultet, Osijek,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
