Pregled bibliografske jedinice broj: 274106
Incorporation of the Unnatural Organometallic Amino Acid 1’ -Aminoferrocene-1-carboxylic Acid (Fca) into Oligopeptides by a Combination of Fmoc and Boc Solid- Phase Synthetic Methods
Incorporation of the Unnatural Organometallic Amino Acid 1’ -Aminoferrocene-1-carboxylic Acid (Fca) into Oligopeptides by a Combination of Fmoc and Boc Solid- Phase Synthetic Methods // European Journal of Inorganic Chemistry, 20 (2006), 4019-4021 (međunarodna recenzija, članak, znanstveni)
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Naslov
Incorporation of the Unnatural Organometallic Amino Acid 1’ -Aminoferrocene-1-carboxylic Acid (Fca) into Oligopeptides by a Combination of Fmoc and Boc Solid- Phase Synthetic Methods
Autori
Barišić, Lidija ; Rapić, Vladimir ; Metzler-Nolte, Nils
Izvornik
European Journal of Inorganic Chemistry (1434-1948) 20
(2006);
4019-4021
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Bioorganometallic Chemistry; Ferrocene; Peptides; Solid-Phase Peptide Synthesis; Unnatural Amino Acids
Sažetak
The organometallic amino acid 1'-aminoferrocene-1-carboxylic acid (Fca) was incorporated interbally into a peptide sequence by solid-phase method combining natural Fmoc-protected amino acids and Boc-Fca-OH to give the pentapeptide Boc-Fca-Ala-Gly-Val-Leu-NH2 (2) and the octapeptide Ac-Val-Gly-Ala-Fca-Ala-Gly-Val-Leu-NH2 (3). Compound 3 was found to have a helically ordered structure by NMR and CD spectroscopy, which stabilized by intramolecular hydrogen bonding in an antiparallel  -sheet-like arrangement.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
Uključenost u ostale bibliografske baze podataka::
- Chemical Abstracts
