Pregled bibliografske jedinice broj: 263217
High pressure synthesis of novel organometallic electron donor - electron acceptor polycyclic dyads
High pressure synthesis of novel organometallic electron donor - electron acceptor polycyclic dyads // The 44th European High Pressure Research Group Conference : Abstracts
Prag, 2006. (poster, nije recenziran, sažetak, znanstveni)
CROSBI ID: 263217 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
High pressure synthesis of novel organometallic electron donor - electron acceptor polycyclic dyads
Autori
Eckert-Maksić, Mirjana ; Margetić, Davor
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
The 44th European High Pressure Research Group Conference : Abstracts
/ - Prag, 2006
Skup
European High Pressure Research Group Conference (44 ; 2006)
Mjesto i datum
Prag, Češka Republika, 04.09.2006. - 08.09.2006
Vrsta sudjelovanja
Poster
Vrsta recenzije
Nije recenziran
Ključne riječi
organometallic dienes; norbornenes; Diels-Alder reaction; 1; 3-dipolar cycloaddition; high pressure
Sažetak
Preparation of novel electron-transfer dyads (donor-acceptor molecules) with novel molecular architecture and well-defined donor/acceptor geometrical orientation is presented. High pressure (HP) promoted synthesis of electron donor-acceptor dyads possessing rigid polynorbornene frameworks and organometallic (7-silanorbornadiene) moiety is discussed in detail. Under HP conditions, cyclic organometallic diene, 1-sila-2, 3, 4, 5-tetraphenyl-1, 1-dimethyl-cyclopenta-2, 4-diene undergoes facile [4p+2p] cycloaddition reactions with functionalized 7-oxanorbornene derivatives giving stereospecifically 7-silanorbornene products in good reaction yields.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
