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Pregled bibliografske jedinice broj: 258009

Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin

Mandić, Zoran; Lopotar, Nevenka
Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin // Electrochemistry communications, 7 (2005), 1; 45-48 doi:10.1016/j.elecom.2004.11.002 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 258009 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin

Autori
Mandić, Zoran ; Lopotar, Nevenka

Izvornik
Electrochemistry communications (1388-2481) 7 (2005), 1; 45-48

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
tylosin ; electroreduction of oxime ; cyclic voltammetry ; preparative scale electrolysis

Sažetak
The electrochemical reduction of 4'- demicarosyl-10-hydro-11-dehydro-11- hydroxyimino-9-carbonyl-9-nor-8a, 9seco-8a-aza- 8a-homorelomycin was investigated by cyclic voltammetry and preparative scale electrolysis. It has been found that oxime group is reduced by ECEC mechanism in a four-electron process. The resulting products of the reduction consisted of the corresponding alpha, beta- unsaturated amine and alpha, beta-saturated ketone. The rate determining step was identified to be the cleavage of N-O bond. In the acidic media the actual leaving group is water and in neutral and moderate basic media hydroxyde ion.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo



POVEZANOST RADA

Projekti:
0125010

Ustanove:
Pliva-Istraživački institut,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Profili:

Avatar Url Zoran Mandić (autor)

Avatar Url Nevenka Lopotar (autor)

Poveznice na cjeloviti tekst rada:

doi doi.org www.sciencedirect.com

Citiraj ovu publikaciju:

Mandić, Zoran; Lopotar, Nevenka
Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin // Electrochemistry communications, 7 (2005), 1; 45-48 doi:10.1016/j.elecom.2004.11.002 (međunarodna recenzija, članak, znanstveni)
Mandić, Z. & Lopotar, N. (2005) Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin. Electrochemistry communications, 7 (1), 45-48 doi:10.1016/j.elecom.2004.11.002.
@article{article, author = {Mandi\'{c}, Zoran and Lopotar, Nevenka}, year = {2005}, pages = {45-48}, DOI = {10.1016/j.elecom.2004.11.002}, keywords = {tylosin, electroreduction of oxime, cyclic voltammetry, preparative scale electrolysis}, journal = {Electrochemistry communications}, doi = {10.1016/j.elecom.2004.11.002}, volume = {7}, number = {1}, issn = {1388-2481}, title = {Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin}, keyword = {tylosin, electroreduction of oxime, cyclic voltammetry, preparative scale electrolysis} }
@article{article, author = {Mandi\'{c}, Zoran and Lopotar, Nevenka}, year = {2005}, pages = {45-48}, DOI = {10.1016/j.elecom.2004.11.002}, keywords = {tylosin, electroreduction of oxime, cyclic voltammetry, preparative scale electrolysis}, journal = {Electrochemistry communications}, doi = {10.1016/j.elecom.2004.11.002}, volume = {7}, number = {1}, issn = {1388-2481}, title = {Electrochemical reduction of 4'-demicarosyl-10-hydro-11-dehydro-11-hydroxyimino-9-carbonyl-9-nor-8a,9seco-8a-aza-8a-homorelomycin, the novel seco compound from the class of tylosin}, keyword = {tylosin, electroreduction of oxime, cyclic voltammetry, preparative scale electrolysis} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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