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Pregled bibliografske jedinice broj: 254722

Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose

Šunjić, Vitomir; Habuš, Ivan; Snatzke, Gunter
Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose // Journal of Organometallic Chemistry, 370 (1989), 1-3; 295-304 doi:10.1016/0022-328X(89)87293-6 (međunarodna recenzija, članak, znanstveni)

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Naslov
Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose

Autori
Šunjić, Vitomir ; Habuš, Ivan ; Snatzke, Gunter

Izvornik
Journal of Organometallic Chemistry (0022-328X) 370 (1989), 1-3; 295-304

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Z-α -acetylaminocinnamic acid ; α -acetylaminoacrylic acid ; bidentate ligands (3 ; 6)

Sažetak
(2R, 3S)-2-Diphenylphosphinomethyl-3-diphenylphosphinotetrahydropyran (3) has been prepared in 64% yield from the dimesylate 5, derived from D-galactose. The surprisingly different reactivities of dimesylates 2 and 5 towards diphenylphosphide anion are considered and the conformational properties of 1-6 discussed in terms of their CD spectra. The rhodium(I) complexes 9 and 10 exhibit low to relatively high enantioselectivities in hydrogenation of Z-α -acetylaminocinnamic acid and α -acetylaminoacrylic acid. The chiroptical and conformational properties of the bidentate ligands (3, 6), and their rhodium(I) complexes (9, 10) are correlated with the observed enantioselectivities.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivan Habuš (autor)

Avatar Url Vitomir Šunjić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Šunjić, Vitomir; Habuš, Ivan; Snatzke, Gunter
Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose // Journal of Organometallic Chemistry, 370 (1989), 1-3; 295-304 doi:10.1016/0022-328X(89)87293-6 (međunarodna recenzija, članak, znanstveni)
Šunjić, V., Habuš, I. & Snatzke, G. (1989) Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose. Journal of Organometallic Chemistry, 370 (1-3), 295-304 doi:10.1016/0022-328X(89)87293-6.
@article{article, author = {\v{S}unji\'{c}, Vitomir and Habu\v{s}, Ivan and Snatzke, Gunter}, year = {1989}, pages = {295-304}, DOI = {10.1016/0022-328X(89)87293-6}, keywords = {Z-α -acetylaminocinnamic acid, α -acetylaminoacrylic acid, bidentate ligands (3, 6)}, journal = {Journal of Organometallic Chemistry}, doi = {10.1016/0022-328X(89)87293-6}, volume = {370}, number = {1-3}, issn = {0022-328X}, title = {Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose}, keyword = {Z-α -acetylaminocinnamic acid, α -acetylaminoacrylic acid, bidentate ligands (3, 6)} }
@article{article, author = {\v{S}unji\'{c}, Vitomir and Habu\v{s}, Ivan and Snatzke, Gunter}, year = {1989}, pages = {295-304}, DOI = {10.1016/0022-328X(89)87293-6}, keywords = {Z-α -acetylaminocinnamic acid, α -acetylaminoacrylic acid, bidentate ligands (3, 6)}, journal = {Journal of Organometallic Chemistry}, doi = {10.1016/0022-328X(89)87293-6}, volume = {370}, number = {1-3}, issn = {0022-328X}, title = {Chiroptical properties and enantioselectivity in hydrogenation with rhodium(I) complexes of chiral bis-diphenylphosphines derived from D-glucose and D-galactose}, keyword = {Z-α -acetylaminocinnamic acid, α -acetylaminoacrylic acid, bidentate ligands (3, 6)} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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