Pregled bibliografske jedinice broj: 254013
The Effect of Thermal Relaxation on the Short-range Order in Melt-Quenched Zr-Co and Zr-Ni Alloys
The Effect of Thermal Relaxation on the Short-range Order in Melt-Quenched Zr-Co and Zr-Ni Alloys // Properties and Applications of Nanocrystalline Alloys from Amorphous Precursiors / Idzikowski, Bogdan ; Švec, Peter ; Miglierini, Marcel (ur.).
Dordrecht : Boston (MA) : London: Kluwer Academic Publishers, 2005. str. 353-362
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Naslov
The Effect of Thermal Relaxation on the Short-range Order in Melt-Quenched Zr-Co and Zr-Ni Alloys
Autori
Kokanović, Ivan ; Tonejc, Antun
Vrsta, podvrsta i kategorija rada
Poglavlja u knjigama, znanstveni
Knjiga
Properties and Applications of Nanocrystalline Alloys from Amorphous Precursiors
Urednik/ci
Idzikowski, Bogdan ; Švec, Peter ; Miglierini, Marcel
Izdavač
Kluwer Academic Publishers
Grad
Dordrecht : Boston (MA) : London
Godina
2005
Raspon stranica
353-362
ISBN
1-4020-2964-0
Ključne riječi
Metallic Glasses, Thermal Stability, Crystallization, Nanocrystal
Sažetak
The Zr803d20 (3d= Co, Ni) metallic glasses and the partially crystalline Zr76Ni24 metallic glass were prepared by melt spinning. The effect of thermal relaxation on the short-range order in melt-quenched the Zr803d20 (3d= Co, Ni) metallic glasses and the partially crystalline Zr76Ni24 metallic glass during heat treatment at different heating rates has been investigated by means of the differential scanning calorimeter, DSC, and the X-ray powder diffraction, XRD, measurements in temperature interval from 300 K to 823 K. According to the XRD results, for the partially crystalline Zr76Ni24 metallic glass, melt-quenched alloy consists of a fraction of metastable Zr3Ni crystalline phase and an amorphous phase. The estimated volume of the fraction of the Zr3Ni crystalline phase was 9.6 %. The crystalline peaks of the Zr3Ni crystalline phase were fitted to the orthorhombic structure type. The Zr3Ni crystallite size was estimated using the Sherrer formula to be from 15 nm to 30 nm. Crystallization studies showed that the existence of the orthorhombic Zr3Ni crystalline phase does not change the thermal stability of the amorphous phase against further crystallization and remains unchanged during the annealing samples up to 823 K. On the basis of the DSC and XRD obtained data it was possible to identify the phases which occur in the heat treatment of the Zr803d20 (3d= Co, Ni) metallic glasses and of the partially crystalline Zr76Ni24 metallic glass up to 823 K. The average crystallite sizes of these nanocrystalline phases were from 10 nm to 24 nm.
Izvorni jezik
Engleski
Znanstvena područja
Fizika
