Pregled bibliografske jedinice broj: 221396
Molybdenum(VI) complexes with tridentate Schiff base ligand, 2-methoxysalicylaldehyde thiosemicarbaone
Molybdenum(VI) complexes with tridentate Schiff base ligand, 2-methoxysalicylaldehyde thiosemicarbaone // Fourteenth Croatian-Slovenian Crystallographic Meeting : Book of abstracts
Zagreb, 2005. str. 55-55 (predavanje, nije recenziran, sažetak, znanstveni)
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Naslov
Molybdenum(VI) complexes with tridentate Schiff base
ligand, 2-methoxysalicylaldehyde thiosemicarbaone
Autori
Strukan, Neven ; Cindrić, Marina ; Vrdoljak, Višnja ; Kamenar, Boris ;
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Fourteenth Croatian-Slovenian Crystallographic Meeting : Book of abstracts
/ - Zagreb, 2005, 55-55
Skup
Fourteenth Croatian-Slovenian Crystallographic Meeting
Mjesto i datum
Vrsar, Hrvatska, 15.06.2005. - 17.06.2005
Vrsta sudjelovanja
Predavanje
Vrsta recenzije
Nije recenziran
Ključne riječi
tiosemikarbazoni ; molibden(VI) kompleksi ; imidazol
(thiosemicarbazones ; molybdenum(VI) complexes ; imidazole)
Sažetak
From reactiona of Mo2(acac)2 with 2.methoxysalicylaldehydw thiosemicarbazone, and after adding of gama-picoline or imidazole two novel molybdenum(VI) complexes were obtained. In both complexes Mo(VI9 atoms are octahedrally coordinated, with a characteristic cis-MoO2 group. Schiff base tridentate ligand is coordinated through one oxygen atoms from salycilaldimine part of the ligand, and one nitrogen and one sulfur atom from thiosemicarbazone part of thw ligand. Additionally, monodentate solvent molecules, gama- picoline in (A), imidazole in (B) are bonded to Mo, thus satisafying octahedral coordination of metal atom.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
