Naslov
Chemical reduction of hematite with starch

Autori
Ellid, M. S. ; Murayed, Y. S. ; Zoto, M. S. ; Musić, Svetozar ; Popović, Stanko

Izvornik
Journal of radioanalytical and nuclear chemistry (0236-5731) 258 (2003), 2; 299-305

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
chemical reduction; hematite; iron oxides

Sažetak
Chemical reduction of hematite with starch in air at elevated temperature was investigated using X-ray powder diffraction, FT-IR and ^57 Moessbauer spectroscopies. On heating the starting mixture for 0.5 and 2 hours at 300 C, magnetite and a small fraction of hematite were identified by XRD. With the heating time prolonged up to 24 hours, magnetite reoxidized and hematite was obtained again. The formation of magnetite was observed even at 580 C. However, the magnetite formed at this temperature was substoichiometric, as shown by XRD and Moessbauer spectroscopy. Characteristic IR bands of oxide phases were monitored by FT-IR spectroscopy. Chemical reduction of hematite with starch into a Fe^o state was not observed in any sample.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA