Pregled bibliografske jedinice broj: 196096
Chiral Chromenes: Synthesis, Separation of Enantiomers and Barriers to Racemization
Chiral Chromenes: Synthesis, Separation of Enantiomers and Barriers to Racemization // Croatica chemica acta, 66 (1993), 1; 209-216 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 196096 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Chiral Chromenes: Synthesis, Separation of Enantiomers and Barriers to Racemization
Autori
Lončar, Linda ; Otočan, Klaudio ; Mintas, Mladen ; Trotsch, Thomas ; Mannschreck, Albrecht
Izvornik
Croatica chemica acta (0011-1643) 66
(1993), 1;
209-216
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
2H-chromenes; enantiomers; separation; barriers to racemization
Sažetak
2H-chromenes 3 and 4 have been synthesized by reduction of the appropriate lactone with diisobutylaluminium hydride and subsequent O-alkylation of the resulting lactols. Separations or enrichments of enantiomers were achieved by liquid chromatography on triacetylcellulose and tribenzoylcellulose, (+)-3 and (-)-3 being separated almost completely, while an enrichment of the enantiomers of 4 was achieved by using the recycling procedure. The barriers for the interconversion of enantiomers of 3 and 4 were determined by thermal racemization of enantiomers.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
