Naslov
Kompleksni spojevi molibdena(VI) s makrocikličkim imino-ligandima
(Molybdenum(VI) complexes with macrocyclic imine ligands)

Autori
Cindrić, Marina ; Užarević, Krunoslav ; Kajfež Novak, Tanja ; Novak, Predrag

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo

Izvornik
Knjiga sažetaka : 19. hrvatski skup kemičara i kemijskih inženjera / Rapić, Vladimir ; Rogošić, Marko - Zagreb : Sveučilišni vjesnik, 2005, 51-51

Skup
19. hrvatski skup kemičara i kemijskih inženjera

Mjesto i datum
Opatija, Hrvatska, 24.04.2005. - 27.04.2005

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
makrociklički ligandi; molibden(VI)
(macrocyclic ligands; molybdenum(VI))

Sažetak
Imine compounds prepared by the reaction of 3-acetyl-6-methyl-2H-pyran-2, 4(3H)-dione (DHA) with various amines are potentially polidentate ligands. DHA is used as antimicrobial and antifungal agent in pharmaceuticals and cosmetics [1]. It is comercially available compound obtained by the autocondensation of ethyl acetoacetate. As part of our research on molybdenum complexes with biologically important organic compounds [2], we have prepared several new molybdenum(VI) complexes with these imine ligands. The complexes have been characterized by chemical and thermogravimetric (TG) analysis, X-ray powder diffraction, IR, 1H NMR, 13C NMR studies and, in some cases, single crystal X-ray diffraction method. [1] E. Mikami, T. Goto, T. Ohno, H. Matsumoto, M.Nishida, J. of Pharm. and Biomed. Analysis 28 (2002) 261-267. [2] M. Cindrić, V. Vrdoljak, T. Kajfež, P. Novak, A. Brbot-Šaranović, N. Strukan, B. Kamenar, Inorg. Chim. Acta 328 (2002) 23-32.

Izvorni jezik
Hrvatski

Znanstvena područja
Kemija

POVEZANOST RADA