Pregled bibliografske jedinice broj: 192217
UV Photoelectron Spectroscopic Study of Substituent Effects in Quinoline Derivatives
UV Photoelectron Spectroscopic Study of Substituent Effects in Quinoline Derivatives // Journal of organic chemistry, 69 (2004), 5005-5010 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 192217 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
UV Photoelectron Spectroscopic Study of Substituent Effects in Quinoline Derivatives
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Journal of organic chemistry (0022-3263) 69
(2004);
5005-5010
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Spectra
Sažetak
The molecular and electronic structure of eight substituted quinolines has been investigated by HeI/HeII photoelectron spectroscopy, Green's function calculations, and comparison with the spectra of related compounds. The correlation between nitrogen lone pair ionization energies and basicity in 18 substituted quinolines is discussed. The influence of different substituents has been quantified via the scheme that is based on experimental energy shifts. The relationships between nitrogen ionization energies, pK(a) values, and medicinal activity are also discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
