Naslov
Nove kiralne nepokretne faze Pirkleovog tipa s miješanim pi-akceptorskim i pi-donorskim svojstvima
(New Pirkle-type chiral stationary phases with mixed pi-acceptor and pi-donor properties)

Autori
Moslavac Forjan, Davorka ; Vinković, Vladimir

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of Abstracts / - , 2004

Skup
ISCD 16, 16th International Symposium on Chirality

Mjesto i datum
Sjedinjene Američke Države, 11.07.2004. - 14.07.2004

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
chirality; chiral stationary phases; HPLC
(kiralnost; kiralne nepokretne faze; HPLC)

Sažetak
All CSPs contain a strong p-acidic N-3, 5-dinitrobenzoyl group, which is expected to interact with p-basic aromatic derivatives, and p-basic naphthyl, 3, 5-dimethylphenyl, anthryl or pyridyl group, which can be utilized for interactions with the p-acidic racemic analytes. The chiral selector is covalently bound at silica surface with the spacer who is placed behind the chiral center, so that in stacionary phase the chiral hole of selector is ideally open for analytes approach.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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