Pregled bibliografske jedinice broj: 1640
Long-Range Electronic Interactions in Androstanediones
Long-Range Electronic Interactions in Androstanediones // International journal of quantum chemistry, 63 (1997), 3; 797-803 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1640 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Long-Range Electronic Interactions in Androstanediones
Autori
Klasinc, Leo ; Paša-Tolić, Ljiljana ; Vikić-Topić, Dražen ; Knop, J.V. ; McGlynn, S.P.
Izvornik
International journal of quantum chemistry (0020-7608) 63
(1997), 3;
797-803
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
steroids; androstanediones long-range electronic effects; MNDO SCF calculations; ^13C-NMR
Sažetak
The results of MNDO SCF MO calculations on 5alpha-androstane (1), androstan-3-one (2), androstan-16-one (3), androstan-17-one (4), androstan-3, 16-dione (5), and androstane-3, 17-dione (6) and the experimental ^13C-NMR chemical shifts observed in various solvents (C_6D_12, CDCl_3, CD_3CO_2D, CD_2Cl_2, CD_3COCD_3, CD_3OD, CD_3CN) were used to assess the nature of long-range interactions between 3, 16- and 3, 17-carbonyl groups in androstanediones. The ^13C-NMR results appear to confirm the proposition that the interactions in androstane-3, 16-dione are stronger.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
