Pregled bibliografske jedinice broj: 162907
Container Systems 1: An Experimental and Theoretical Study of the High-Pressure Intramolecular Cycloaddition of Tethered Furans and Anthracenes onto Cyclobutene-1, 2-diesters
Container Systems 1: An Experimental and Theoretical Study of the High-Pressure Intramolecular Cycloaddition of Tethered Furans and Anthracenes onto Cyclobutene-1, 2-diesters // ECSOC-8, 8th Electronic Conference on Synthetic Organic Chemistry / Julio A. Seijas Vázquez, Shu-Kun Lin, De-Chun Ji (ur.).
-: -, 2004. str. - (poster, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)
CROSBI ID: 162907 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Container Systems 1: An Experimental and Theoretical Study of the High-Pressure Intramolecular Cycloaddition of Tethered Furans and Anthracenes onto Cyclobutene-1, 2-diesters
Autori
Margetić, Davor ; Warrener, Ronald N.
Vrsta, podvrsta i kategorija rada
Radovi u zbornicima skupova, cjeloviti rad (in extenso), znanstveni
Izvornik
ECSOC-8, 8th Electronic Conference on Synthetic Organic Chemistry
/ Julio A. Seijas Vázquez, Shu-Kun Lin, De-Chun Ji - , 2004
Skup
ECSOC-8, 8th Electronic Conference on Synthetic Organic Chemistry
Mjesto i datum
,
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
-
Sažetak
High pressure reaction of cyclobutene-1, 2-difurfuryl esters form thermally labile intramolecular Diels-Alder adducts at high pressure. This high pressure protection of a cyclobutene pi-bond is used to explain why reaction of cyclobutene 1, 2-di-furfuryl ester and dimethyl acetylenedicarboxylate forms the 1:1-adduct at one furan site and leaving the second furan untouched, even with excess dienophile. Intramolecular anthracene cycloadditions and alternative cyclodaddition synthetic routes to polycyclic oligonorbornene container structures are also discussed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
