Photochemical Formation of Novel Pyrrolo[3, 2-b]-6, 7-benzobicyclo[3.2.1]octa-2, 6-diene

Basarić, Nikola; Marinić, Željko; Šindler-Kulyk, Marija

Pregled bibliografske jedinice broj: 140096

Photochemical Formation of Novel Pyrrolo[3, 2-b]-6, 7-benzobicyclo[3.2.1]octa-2, 6-diene

Basarić, Nikola; Marinić, Željko; Šindler-Kulyk, Marija

Photochemical Formation of Novel Pyrrolo[3, 2-b]-6, 7-benzobicyclo[3.2.1]octa-2, 6-diene // Journal of Organic Chemistry, 68 (2003), 19; 7524-7527 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 140096 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Photochemical Formation of Novel Pyrrolo[3, 2-b]-6, 7-benzobicyclo[3.2.1]octa-2, 6-diene

Autori
Basarić, Nikola ; Marinić, Željko ; Šindler-Kulyk, Marija

Izvornik
Journal of Organic Chemistry (0022-3263) 68 (2003), 19; 7524-7527

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
pyrrole; photochemical cycloaddition; benzobicyclo[3.2.1]octa-2; 6-diene

Sažetak
The first synthesis of 1, 4, 9, 10-tetrahydro-4, 9-methanobenzo[4, 5]cyclohepta[1, 2-b]pyrrole (11) is achieved by photochemical intramolecular [2+2] cycloaddition of N-phenoxycarbonyl- (5a) and N-ethoxycarbonyl-2-[2-(2-vinylphenyl)]pyrrole (6a), respectively followed by basic hydrolysis of the isolated N-substituted 1, 4, 9, 10-tetrahydro-4, 9-methanobenzo[4, 5]cyclohepta[1, 2-b]pyrroles (10a, 10b). Some competitively formed products are also isolated.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
0098059
0125004

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Profili:

Marija Šindler (autor)