Pregled bibliografske jedinice broj: 1282530
Effect of Passivating Molecules and Antisolvents on Lifetime of Green Dion–Jacobson Perovskite Light-Emitting Diodes
Effect of Passivating Molecules and Antisolvents on Lifetime of Green Dion–Jacobson Perovskite Light-Emitting Diodes // ACS applied materials & interfaces, 15 (2023), 25; 30083-30092 doi:10.1021/acsami.3c02170 (međunarodna recenzija, članak, znanstveni)
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Naslov
Effect of Passivating Molecules and Antisolvents
on Lifetime of Green Dion–Jacobson Perovskite
Light-Emitting Diodes
Autori
Qin, Xinshun ; He, Yanling ; Tao, Chun Ki ; Sergeev, Aleksandr ; Wong, Kam Sing ; Ren, Zhilin ; Liang, Qiong ; Leung, Tik Lun ; Li, Gang ; Popović, Jasminka ; Ng, Alan Man Ching ; Djurišić, Aleksandra B.
Izvornik
ACS applied materials & interfaces (1944-8244) 15
(2023), 25;
30083-30092
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Dion–Jacobson Perovskite
Sažetak
We investigated the influence of two passivating molecules containing a P═O group on the performance of quasi-2D Dion–Jacobson halide perovskite light-emitting diodes, namely, triphenylphosphine oxide (TPPO) and diphenyl-4- triphenylsilylphenyl phosphine oxide (TSPO1). We found that both passivating molecules lead to increased efficiency compared to control devices, while they had opposite effects on device lifetime, with a decrease observed for TPPO and an increase observed for TSPO1. The two passivating molecules resulted in differences in energy-level alignment, electron injection, film morphology and crystallinity, and ion migration during operation. While TPPO resulted in improved photoluminescence decay times, overall higher maximum external quantum efficiency (EQE) and device lifetime were obtained for TSPO1 compared to TPPO (14.4% vs 12.4% EQE, 341 min vs 42 min T50).
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE