Pregled bibliografske jedinice broj: 1278141
Recycling of PET Post-consumer Bottles: Effect of the Re-extrusion Process on the Structure, Thermal Properties, and Apparent Activation Energy
Recycling of PET Post-consumer Bottles: Effect of the Re-extrusion Process on the Structure, Thermal Properties, and Apparent Activation Energy // Kemija u industriji : časopis kemičara i tehnologa Hrvatske, 72 (2023), 5-6; 381-388 doi:10.15255/KUI.2022.072 (međunarodna recenzija, članak, stručni)
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Naslov
Recycling of PET Post-consumer Bottles: Effect of the Re-extrusion Process on the Structure, Thermal Properties, and Apparent Activation Energy
Autori
Jakić, Miće ; Perinović Jozić, Sanja ; Bandić, Ivana ; Ključe, Laura
Izvornik
Kemija u industriji : časopis kemičara i tehnologa Hrvatske (0022-9830) 72
(2023), 5-6;
381-388
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, stručni
Ključne riječi
Poly(ethylene terephthalate), post-consumer bottles, recycling, re-extrusion, thermal properties, activation energy
Sažetak
In this work, post-consumer poly(ethylene terephthalate) (PET) bottles were gathered, separated from other materials, and re-extruded. In order to evaluate the effect of re-extrusion on the structure of PET, Fourier transform infrared spectroscopy was utilised. No significant effect of the re-extrusion process on the structure of the PET sample was noticed. Obtained samples were also characterised by differential scanning calorimetry (DSC) in order to determine characteristic thermal transitions of PET. DSC results indicated the influence of re-extrusion ; extruded PET started to melt at lower temperatures, and the crystallisation of re-extruded PET took place at significantly higher temperatures in comparison to PET. Likewise, thermogravimetric analysis (TG) was used to evaluate the effect of re-extrusion process on the thermal stability of samples. TG analysis revealed that the re-extrusion process had no effect on the thermal stability of the investigated PET samples. Finally, the activation energy of thermal degradation of the investigated samples was calculated using iso-conversional Flynn-Wall-Ozawa and Friedman method. Consequently, higher activation energies were noticed for the re-extruded PET sample in comparison to the PET bottle sample, which is a good argument in support of PET bottle recycling.
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
POVEZANOST RADA
Ustanove:
Kemijsko-tehnološki fakultet, Split
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Emerging Sources Citation Index (ESCI)