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Pregled bibliografske jedinice broj: 1276566

Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy


Vujević, Lucija; Karadeniz, Bahar; Cindro Nikola; Avdoshenko, Stanislav M.; Popov, Alexey A.; Žilić, Dijana; Užarević, Krunoslav; Kveder, Marina
Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy // V. simpozij supramolekulske kemije : knjiga sažetaka = Supramolecular Chemistry 2022 : Book of Abstracts / Frkanec, Leo ; Namjesnik, Danijel ; TomiÅ”ić, Vladislav (ur.).
Zagreb: Institut Ruđer BoÅ”ković, 2022. str. 28-28 (poster, nije recenziran, sažetak, znanstveni)


CROSBI ID: 1276566 Za ispravke kontaktirajte CROSBI podrŔku putem web obrasca

Naslov
Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy

Autori
Vujević, Lucija ; Karadeniz, Bahar ; Cindro Nikola ; Avdoshenko, Stanislav M. ; Popov, Alexey A. ; Žilić, Dijana ; Užarević, Krunoslav ; Kveder, Marina

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
V. simpozij supramolekulske kemije : knjiga sažetaka = Supramolecular Chemistry 2022 : Book of Abstracts / Frkanec, Leo ; Namjesnik, Danijel ; TomiÅ”ić, Vladislav - Zagreb : Institut Ruđer BoÅ”ković, 2022, 28-28

Skup
V. simpozij supramolekulske kemije = Supramolecular Chemistry 2022

Mjesto i datum
Zagreb, Hrvatska, 08.12.2022

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
metal-organic frameworks ; copper ; molecular spin qubits ; pulsed EPR spectroscopy

Sažetak
The spin-lattice (š‘‡1) and phase-memory electron spin (š‘‡š‘š) relaxation times of metal-organic frameworks (MOFs) MOF-525 and PCN-223 doped with 10% copper (II) ions were examined by pulse electron paramagnetic resonance (EPR) spectroscopy. Investigation of these MOFs was performed in order to determine their potential as molecular spin qubits. Both MOFs exhibit electron spin coherence detectable up to 80 K. MOF-525 shows longer relaxation times than PCN-223. Incorporation of fullerene into PCN-223 increases both spin-lattice and phase-memory electron spin relaxation times. It was observed that PCN-223 with a maximum filling of fullerene shows better performance in both relaxation times compared with the previously surpassing MOF-525.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA


Projekti:
HRZZ-PZS-2019-02-4129 - Mehanokemijske i bezotopinske strategije za sintezu funkcionalnih poroznih materijala s naprednim fizičko-kemijskim i katalitičkim svojstvima (MECHADVANCE) (Užarević, Krunoslav, HRZZ - 2019-02) ( CroRIS)
HRZZ-IP-2018-01-3168 - Studija važnosti spinskih međudjelovanja kao osnova za nove pristupe u istraživanju materijala (SPES) (Ilakovac-Kveder, Marina, HRZZ - 2018-01) ( CroRIS)

Ustanove:
Institut "Ruđer BoÅ”ković", Zagreb

Poveznice na cjeloviti tekst rada:

supramolchem.org

Citiraj ovu publikaciju:

Vujević, Lucija; Karadeniz, Bahar; Cindro Nikola; Avdoshenko, Stanislav M.; Popov, Alexey A.; Žilić, Dijana; Užarević, Krunoslav; Kveder, Marina
Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy // V. simpozij supramolekulske kemije : knjiga sažetaka = Supramolecular Chemistry 2022 : Book of Abstracts / Frkanec, Leo ; Namjesnik, Danijel ; TomiÅ”ić, Vladislav (ur.).
Zagreb: Institut Ruđer BoÅ”ković, 2022. str. 28-28 (poster, nije recenziran, sažetak, znanstveni)
Vujević, L., Karadeniz, B., Cindro Nikola, Avdoshenko, S., Popov, A., Žilić, D., Užarević, K. & Kveder, M. (2022) Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy. U: Frkanec, L., Namjesnik, D. & TomiÅ”ić, V. (ur.)V. simpozij supramolekulske kemije : knjiga sažetaka = Supramolecular Chemistry 2022 : Book of Abstracts.
@article{article, author = {Vujevi\'{c}, Lucija and Karadeniz, Bahar and Avdoshenko, Stanislav M. and Popov, Alexey A. and \v{Z}ili\'{c}, Dijana and U\v{z}arevi\'{c}, Krunoslav and Kveder, Marina}, year = {2022}, pages = {28-28}, keywords = {metal-organic frameworks, copper, molecular spin qubits, pulsed EPR spectroscopy}, title = {Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy}, keyword = {metal-organic frameworks, copper, molecular spin qubits, pulsed EPR spectroscopy}, publisher = {Institut Ru\djer Bo\v{s}kovi\'{c}}, publisherplace = {Zagreb, Hrvatska} }
@article{article, author = {Vujevi\'{c}, Lucija and Karadeniz, Bahar and Avdoshenko, Stanislav M. and Popov, Alexey A. and \v{Z}ili\'{c}, Dijana and U\v{z}arevi\'{c}, Krunoslav and Kveder, Marina}, year = {2022}, pages = {28-28}, keywords = {metal-organic frameworks, copper, molecular spin qubits, pulsed EPR spectroscopy}, title = {Electron Spin Relaxation Times of Copper(II) Ions in MOF-525 and PCN223 Measured by Pulsed EPR Spectroscopy}, keyword = {metal-organic frameworks, copper, molecular spin qubits, pulsed EPR spectroscopy}, publisher = {Institut Ru\djer Bo\v{s}kovi\'{c}}, publisherplace = {Zagreb, Hrvatska} }




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