Pretraga

Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1269729

Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs

Ibrahim, A.; Arita, Y.; Ali, A.S.; Khan, I.; Zhang, B.; Razum, Marta; Pavić, Luka; Šantić, Ana; Homonnay, Z.; Kuzmann, E. et al.
Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs // Journal of physics and chemistry of solids, 179 (2023), 111391, 12 doi:10.1016/j.jpcs.2023.111391 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 1269729 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs

Autori
Ibrahim, A. ; Arita, Y. ; Ali, A.S. ; Khan, I. ; Zhang, B. ; Razum, Marta ; Pavić, Luka ; Šantić, Ana ; Homonnay, Z. ; Kuzmann, E. ; Hassaan, M.Y. ; Wang, J. ; Kubuki, S.

Izvornik
Journal of physics and chemistry of solids (0022-3697) 179 (2023); 111391, 12

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
LIBs ; Cathode materials ; XAFS ; XRD ; DC conductivity ; Mossbauer spectroscopy

Sažetak
Due to their low cost and non-toxic characteristics, iron-vanadium-phosphate glass and glass ceramics as a cathode in lithium-ion batteries (LIBs) promise an excellent storage system. The impact of adding Fe2O3 has been studied on the local structure, electric conductivity, and battery performance of xFe2O3-(60-x)V2O5-40P2O5(10≤x≤50mol%) glass and glass ceramics, abbreviated as xFVP, were prepared by the melt quenching method. The xFVP glass and glass-ceramics series were scientifically studied before (BHT) and after heat treatment (HT) at 500 ◦C for 100 min. The X-ray diffraction patterns (XRD), 57Fe-Mossbauer spectra (FeMS), X-ray absorption fine structure (XAFS), Fourier transform infrared spectroscopy (FTIR), DC conductivity, and charge-discharge capacity were achieved in this study. The XRD data of xFVP-BHT glasses confirmed the amorphous nature as ’x’ increased from 10 to 30 mol%. Also, we found several sharp diffraction lines in the XRD patterns of xFVP-BHT and xFVP-HT, which are attributed to the FePO4, Fe3.5(PO4)3, (VO)(PO4), FePVO6, and V2O5 crystalline phases. Furthermore, with Fe2O3 increasing from 10 to 50 mol%, the DC conductivity of xFVP glass ceramics at room temperature decreased from 1.14 × 10-6 (Ω cm)-1 to 5.99 × 10-8 (Ω cm)-1. The highest initial capacity is 342 mAh g-1 recorded in 10FVP-BHT, measured at a current density of 50 mA g-1. In conclusion, Fe ions were added to the phosphate-vanadate glass to enhance the local structure and improve the cyclability of xFVP glasses as a cathode, making these glasses a promising active material for high-performance cathode LIBs.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ana Šantić (autor)

Avatar Url Marta Razum (autor)

Avatar Url Luka Pavić (autor)

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com

Citiraj ovu publikaciju:

Ibrahim, A.; Arita, Y.; Ali, A.S.; Khan, I.; Zhang, B.; Razum, Marta; Pavić, Luka; Šantić, Ana; Homonnay, Z.; Kuzmann, E. et al.
Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs // Journal of physics and chemistry of solids, 179 (2023), 111391, 12 doi:10.1016/j.jpcs.2023.111391 (međunarodna recenzija, članak, znanstveni)
Ibrahim, A., Arita, Y., Ali, A., Khan, I., Zhang, B., Razum, M., Pavić, L., Šantić, A., Homonnay, Z. & Kuzmann, E. (2023) Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs. Journal of physics and chemistry of solids, 179, 111391, 12 doi:10.1016/j.jpcs.2023.111391.
@article{article, author = {Ibrahim, A. and Arita, Y. and Ali, A.S. and Khan, I. and Zhang, B. and Razum, Marta and Pavi\'{c}, Luka and \v{S}anti\'{c}, Ana and Homonnay, Z. and Kuzmann, E. and Hassaan, M.Y. and Wang, J. and Kubuki, S.}, year = {2023}, pages = {12}, DOI = {10.1016/j.jpcs.2023.111391}, chapter = {111391}, keywords = {LIBs, Cathode materials, XAFS, XRD, DC conductivity, Mossbauer spectroscopy}, journal = {Journal of physics and chemistry of solids}, doi = {10.1016/j.jpcs.2023.111391}, volume = {179}, issn = {0022-3697}, title = {Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs}, keyword = {LIBs, Cathode materials, XAFS, XRD, DC conductivity, Mossbauer spectroscopy}, chapternumber = {111391} }
@article{article, author = {Ibrahim, A. and Arita, Y. and Ali, A.S. and Khan, I. and Zhang, B. and Razum, Marta and Pavi\'{c}, Luka and \v{S}anti\'{c}, Ana and Homonnay, Z. and Kuzmann, E. and Hassaan, M.Y. and Wang, J. and Kubuki, S.}, year = {2023}, pages = {12}, DOI = {10.1016/j.jpcs.2023.111391}, chapter = {111391}, keywords = {LIBs, Cathode materials, XAFS, XRD, DC conductivity, Mossbauer spectroscopy}, journal = {Journal of physics and chemistry of solids}, doi = {10.1016/j.jpcs.2023.111391}, volume = {179}, issn = {0022-3697}, title = {Impact of adding Fe ions on the local structure and electrochemical performance of P2O5–V2O5 glass and glass ceramics used as a cathode in LIBs}, keyword = {LIBs, Cathode materials, XAFS, XRD, DC conductivity, Mossbauer spectroscopy}, chapternumber = {111391} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

Citati:

    Altmetrijski pokazatelji:


    Podijeli:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font
    CROSBI koristi kolačiće (cookies) kako bi poboljšao funkcionalnost stranice.