Pregled bibliografske jedinice broj: 1244514
Cyclobutanetetraamino acid derived homochiral metal- organic frameworks
Cyclobutanetetraamino acid derived homochiral metal- organic frameworks // 27th Croatian Meeting of Chemists and Chemical Engineers and 5th Symposium Vladimir Prelog : Book of Abstracts / Marković, Dean ; Meštrović, Ernest ; Namjesnik, Danijel ; Tomašić, Vesna (ur.).
Zagreb, 2021. str. 247-247 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 1244514 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Cyclobutanetetraamino acid derived homochiral metal-
organic frameworks
Autori
Talajić, Gregor ; Brekalo, Ivana ; Topić, Edi ; Cindro, Nikola ; Užarević, Krunoslav
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
27th Croatian Meeting of Chemists and Chemical Engineers and 5th Symposium Vladimir Prelog : Book of Abstracts
/ Marković, Dean ; Meštrović, Ernest ; Namjesnik, Danijel ; Tomašić, Vesna - Zagreb, 2021, 247-247
Skup
27. hrvatski skup kemičara i kemijskih inženjera (27HSKIKI) ; 5. simpozij Vladimir Prelog
Mjesto i datum
Mali Lošinj, Hrvatska, 05.10.2021
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
MOF ; chiral separation ; amino acid
Sažetak
Homochiral metal-organic frameworks (MOF) have been gaining increasing attention as novel chiral stationary phase materials for chromatographic separations in the past decade due to their high porosity and chemical stability.[1, 2, 3] In an effort to find new homochiral MOFs we synthesized a series of tetratopic, D2 symmetric linkers by coupling trans, trans, trans- cyclobutanetetracarboxylic acid and various amino acid benzyl esters followed by hydrogenolysis of the ester protecting groups. These linkers, easily prepared on multigram scale, were used in the synthesis of zirconium based MOFs whose performance as chiral stationary phase materials is being evaluated in resolutions of various racemic mixtures of small molecules.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Krunoslav Užarević (autor)
Ivana Brekalo (autor)
Gregor Talajić (autor)
Edi Topić (autor)
Nikola Cindro (autor)