Naslov
Hydrogen bonding patterns in some ferrocene compounds. Synthesis, spectroscopy and single crystal x-ray diffractometry

Autori
Pavlović, Gordana ; Barišić, Lidija ; Lapić, Jasmina ; Rapić, Vladimir

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Abstracts of the CrystEngComm Discussion 1 : Innovation in Crystal Engineering / - Bristol, 2002

Skup
CrystEngComm Discussion 1 : Innovation in Crystal Engineering

Mjesto i datum
Bristol, Ujedinjeno Kraljevstvo, 29.06.2002. - 01.07.2002

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
ferrocene; amino acids; hydrogen bonding patterns; X-ray crystal structures

Sažetak
Metallocenes and their derivatives are hydrophobic, neutral compounds soluble in organic solvents. They can easily cross cellular membranes and, according to the above mentioned properties, can perform therapeutic and investigation purposes in biochemistry, microbiology and medicine. The conformational flexibility and the redox properties of metallocene complexes play important role in their various applications in the area of bioorganometallic chemistry. Metal-containing polymeric materials with cyclopentadienyl moieties are very attractive materials for electronic, magnetic and optical uses. The electronic properties of ferrocene derivatives are considerably influenced by the presence of different functional groups on cyclopentadienyl rings (acyl, carboxy, derived functional groups, etc.) implicating potentially different applications of these complexes. Differently functionalized ferrocene derivatives can reveal various types of hydrogen bonds such as N-H...O=C, O-H...O and C-H...O bonds responsible for the molecular features in the crystalline state.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA