Pregled bibliografske jedinice broj: 1236164
Nanoarchitectured superparamagnetic iron oxide-doped mesoporous carbon nanozymes for glucose sensing
Nanoarchitectured superparamagnetic iron oxide-doped mesoporous carbon nanozymes for glucose sensing // Sensors and Actuators B: Chemical, 366 (2022), 131980-131991 doi:10.1016/j.snb.2022.131980 (međunarodna recenzija, članak, znanstveni)
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Naslov
Nanoarchitectured superparamagnetic iron oxide-doped
mesoporous carbon nanozymes for glucose sensing
Autori
Md A., Wahaba ; S. M. Azad, Hossaina ; Mostafa Kamal, Masud ; Hyeongyu, Park ; Aditya, Ashok ; Mislav, Mustapić ; Minjun, Kim ; Dipak, Patel ; Mahboobeh, Shahbazi ; Md. Shahriar, A.Hossaina ; Yusuke, Yamauchi ; Yusuf Valentino, Kaneti
Izvornik
Sensors and Actuators B: Chemical (0925-4005) 366
(2022);
131980-131991
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Mesoporous carbon, Iron oxides, Peroxidase mimicking, Nanozymes, Glucose detection, Biosensors
Sažetak
The incorporation of nanoarchitectonics into the development of nanozymes to achieve target- specific geometry, dense active sites, and cascade catalysis is highly demanded for developing ultrasensitive bioassays. The improved dispersion and uniform distribution of metal active sites onto a three-dimensional (3D) mesoporous carbon support (MC) with a high surface area can lead to enhanced substrate binding, mobility, and collision probability and therefore, increased peroxidase mimetic activity. Herein, we report the fabrication of well-dispersed superparamagnetic iron oxide (IO) nanoparticles (NPs) on mesoporous carbon (IO-MC) support with high Fe3+ active sites, high surface area, and ordered mesoporous pore channels that show promising catalytic activity at room temperature. The as-prepared IO- MC shows good nanozyme activity at room temperature with highly favorable Michaelis-Menten constant, Km (0.242 mM) and fast reaction rate (0.193 × 10−7 MS−1). Finally, we demonstrate the functionality and pre-eminence of IO-MC nanozyme for bioassay. As a proof-of-concept, we develop a superior glucose assay that provides a LOD (limit of detection) of 2 µM in the spiked sample. These findings suggest that homogeneously dispersed iron oxide NPs on MC show promising potential as next- generation nanozyme for developing sensitive bioassays.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija, Interdisciplinarne prirodne znanosti
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus