Naslov
Mechanically flexible crystals of cadmium(II) coordination polymers

Autori
Pisačić, Mateja

Vrsta, podvrsta i kategorija rada
Ocjenski radovi, doktorska disertacija

Fakultet
Prirodoslovno-matematički fakultet

Mjesto
Zagreb

Datum
24.11

Godina
2022

Stranica
94

Mentor
Đaković, Marijana

Ključne riječi
coordination polymers ; flexible crystals ; intermolecular interactions ; mechanically induced response

Sažetak
Mechanically responsive crystals have recently attracted the attention of a wide scientific community, but the origin of this remarkable crystal behaviour is still unclear. This thesis provides a systematic study of mechanically induced crystal flexibility on a series of one- dimensional crystalline cadmium(II) coordination polymers, which provided a valuable dataset of different structural architectures, morphologies, and an unexpectedly wide range of variable mechanical responses. A detailed and systematic correlation of the structural features and mechanical responses using advanced experimental and computational methods, provided a deeper insight into the origin and mechanism of mechanically induced flexibility. It was shown that the relative strength and directionality of intermolecular interactions are one of the key parameters in delivering a specific mechanical response. Thorough research emphasized further importance of the direction-dependent responses, and obtained results provided a fruitful avenue of potential practical applications.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA