Pregled bibliografske jedinice broj: 1230519
The role of the A-site cation and crystal structure on the electrical conductivity of strontium-doped calcium and barium manganites
The role of the A-site cation and crystal structure on the electrical conductivity of strontium-doped calcium and barium manganites // Journal of alloys and compounds, 935 (2023), 1; 167949, 11 doi:10.1016/j.jallcom.2022.167949 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1230519 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
The role of the A-site cation and crystal
structure on the electrical conductivity of
strontium-doped calcium and barium manganites
Autori
Žužić, Andreja ; Pavić, Luka ; Bafti, Arijeta ; Marijan, Sara ; Macan, Jelena ; Gajović, Andreja
Izvornik
Journal of alloys and compounds (0925-8388) 935
(2023), 1;
167949, 11
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
autocombustion ; barium manganite ; calcium manganite ; coprecipitation synthesis ; electrical properties
Sažetak
The influence of A-site cation doping, crystal structure and structural defects (oxygen nonstoichiometry) on the electrical conductivity of Sr-doped CaMnO3 (CSMO) and BaMnO3 (BSMO) was investigated. CSMO and BSMO were prepared by citrate-nitrate autocombustion and coprecipitation synthesis, pressed into pellets and sintered. Since the oxygen nonstoichiometry in CSMO was uniform, the increase in electrical conductivity was primarily caused by the increase in Sr content. On the other hand, the oxygen nonstoichiometry in BSMO was more pronounced and it decreased with Sr- doping. Therefore, the highest conductivities were obtained for the undoped BaMnO3 samples. The electrical conductivities of CSMO were similar to those of widely investigated rare-earth manganites and more than 10^4 times higher than those of BSMO. Therefore, CSMO has the potential to be a low-cost cathode material in solid oxide fuel cells.
Izvorni jezik
Engleski
Znanstvena područja
Interdisciplinarne prirodne znanosti, Kemijsko inženjerstvo, Interdisciplinarne tehničke znanosti
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-5246 - Nanokompoziti s perovskitima za fotovoltaike, fotokatalizu i senzoriku (NanoPeroPhotoSens) (Gajović, Andreja, HRZZ - 2018-01) ( CroRIS)
EK-EFRR-KK.01.1.1.02.0022 - Virtulab – Integrirani laboratorij za primarne i sekundarne sirovine (Virtulab) (Borojević Šoštarić, Sibila; Šantek, Božidar; Rogošić, Marko; Petrović, Igor; Zovko Brodarac, Zdenka, EK - KK.01.1.1.02) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Arijeta Bafti
(autor)
Andreja Gajović
(autor)
Andreja Žužić
(autor)
Jelena Macan
(autor)
Sara Marijan
(autor)
Luka Pavić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus