Naslov
Methyl 3-ferrocenylpropanoate

Autori
Cetina, Mario ; Mrvoš-Sermek, Draginja ; Jukić, Marijana ; Rapić, Vladimir

Izvornik
Acta crystallographica. Section E, Structure reports online (1600-5368) E58 (2002), 11; M676-m678

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Single-crystal X-ray study ; T = 295K ; Mean sigma(C-C) = 0.003 A ; R factor = 0.036 ; wR factor = 0.099 ; Data-to-parameter ratio = 20.9

Sažetak
The title compound, Fe(C_5H_5)(C_9H_11O_2), was prepared and characterized by spectroscopic methods and crystal structure determination. The average values of the bond distances between the C atoms in the cyclopentadienyl rings are 1.422(3)A in the substituted and 1.404(4)A in the unsubstituted ring. The Fe-C bond angles in both rings range from 107.1(2) to 108.9(2)o. The cyclopentadienyl rings are almost parallel and deviate only slightly from the eclipsed conformation. The molecules are connected into dimers by very weak C-H· ; · ; O intermolecular hydrogen bonds.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA