Pregled bibliografske jedinice broj: 1209957
Simulation of two electrode reactions coupled by the chemical reaction
Simulation of two electrode reactions coupled by the chemical reaction // Turkish journal of chemistry, 46 (2022), 4; 1226-1233 doi:10.55730/1300-0527.3429 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1209957 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Simulation of two electrode reactions coupled by the
chemical reaction
Autori
Lovrić, Milivoj
Izvornik
Turkish journal of chemistry (1300-0527) 46
(2022), 4;
1226-1233
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ECE mechanism ; Rotating disk electrode ; Staircase cyclic voltammetry ; Simulation ; Polarographic wave.
Sažetak
A model of an ECE mechanism consisting of two reversible electrode reactions coupled by the kinetically controlled, second order, reversible chemical reaction is developed for the staircase cyclic voltammetry on the rotating disk electrode. The relationship between the limiting current of the second wave and the rate constant of chemical reaction is investigated. The concentration of electroinactive component of the forward reaction influences the half-wave potential of the first wave and the limiting current of the second wave. The responses of the mechanisms with reversible and irreversible chemical reactions are compared.
Izvorni jezik
Engleski
Napomena
Posvećeno sjećanju na Dr Šebojku Komorsky-Lovrić.
