Pretraga

Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1198906

Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline

Vušak, Darko; Ležaić, Katarina; Jurec, Jurica; Žilić, Dijana; Prugovečki, Biserka
Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline // Heliyon, 8 (2022), 6; E09556, 18 doi:https://.org/10.1016/j.heliyon.2022.e09556 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 1198906 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline

Autori
Vušak, Darko ; Ležaić, Katarina ; Jurec, Jurica ; Žilić, Dijana ; Prugovečki, Biserka

Izvornik
Heliyon (2405-8440) 8 (2022), 6; E09556, 18

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Ternary coordination compounds ; Solvatomorphs ; Crystal structures ; ESR spectra ; Solution-based synthesis ; Mechanochemical synthesis ; Copper complexes ; L-threonine ; 1, 10-Phenanthroline

Sažetak
Solution-based and solid-state reactions of copper(ii) compounds, 1, 10-phenanthroline and l- threonine were investigated. Eight new ternary coordination compounds were obtained: [Cu(l-Thr)(H2O)(phen)]2SO4∙10H2O (1a∙10H2O), [Cu(l-Thr)(H2O) (phen)]2SO4∙4.3H2O (1a∙4.3H2O), {;[Cu(μ-l-Thr)(phen)]2SO4∙3.5H2O};n (1b∙3.5H2O), [Cu(l-Thr)(H2O)(phen)][Cu(l-Thr)(CH3OH) (phen)]SO4∙2H2O∙CH3OH (1c∙2H2O∙CH3OH), [Cu(l-Thr) (H2O)(phen)][Cu(l-Thr)(CH3OH)(phen)]SO4∙4H2O (1c∙4H2O), [Cu(l-Thr)(CH3OH)(phen)]2SO4∙H2O (1d∙H2O), [Cu(l-Thr)(H2O)(phen)][Cu(l-Thr)(CH3OH) (phen)][Cu(SO4)(l-Thr)(phen)]HSO4∙H2O∙3CH3OH (1e·H2O·3CH3OH), [Cu(l-Thr)(H2O)(phen)][Cu(l-Thr) (phen)(py)]SO4 (1f) (phen = 1, 10-phenanthroline, l-Thr = l-threoninate, py = pyridine). X-ray crystal structure analysis of the prepared ternary coordination compounds revealed extensive hydrogen bonding and π-interactions that link complex species, anions and solvent molecules into 3D architectures. The water/methanol solvent molecules are found in pockets and/or channels in seven solvates. ESR spectra of different types of compounds were also investigated. In all measured compounds the unpaired electron of the copper(II) ion is located in the dx2-y2 orbital which is in agreement with elongated square-pyramidal geometry. Compound 1a∙10H2O showed substantial cytotoxic activity toward human hepatocellular carcinoma (HepG2) and acute monocytic leukaemia (THP-1) cell lines.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
HRZZ-IP-2018-01-3168 - Studija važnosti spinskih međudjelovanja kao osnova za nove pristupe u istraživanju materijala (SPES) (Ilakovac-Kveder, Marina, HRZZ - 2018-01) ( CroRIS)
EK-EFRR-KK.01.1.1.02.0016 - Centar izvrsnosti u kemiji - CIuK (CIuK) (Požar, Josip; Rubčić, Mirta; Biljan, Ivana, EK - KK.01.1.1.02) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Avatar Url Biserka Prugovečki (autor)

Avatar Url Darko Vusak (autor)

Avatar Url Jurica Jurec (autor)

Avatar Url Dijana Žilić (autor)

Poveznice na cjeloviti tekst rada:

doi www.cell.com

Citiraj ovu publikaciju:

Vušak, Darko; Ležaić, Katarina; Jurec, Jurica; Žilić, Dijana; Prugovečki, Biserka
Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline // Heliyon, 8 (2022), 6; E09556, 18 doi:https://.org/10.1016/j.heliyon.2022.e09556 (međunarodna recenzija, članak, znanstveni)
Vušak, D., Ležaić, K., Jurec, J., Žilić, D. & Prugovečki, B. (2022) Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline. Heliyon, 8 (6), E09556, 18 doi:https://.org/10.1016/j.heliyon.2022.e09556.
@article{article, author = {Vu\v{s}ak, Darko and Le\v{z}ai\'{c}, Katarina and Jurec, Jurica and \v{Z}ili\'{c}, Dijana and Prugove\v{c}ki, Biserka}, year = {2022}, pages = {18}, DOI = {https://doi.org/10.1016/j.heliyon.2022.e09556}, chapter = {E09556}, keywords = {Ternary coordination compounds, Solvatomorphs, Crystal structures, ESR spectra, Solution-based synthesis, Mechanochemical synthesis, Copper complexes, L-threonine, 1, 10-Phenanthroline}, journal = {Heliyon}, doi = {https://doi.org/10.1016/j.heliyon.2022.e09556}, volume = {8}, number = {6}, issn = {2405-8440}, title = {Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline}, keyword = {Ternary coordination compounds, Solvatomorphs, Crystal structures, ESR spectra, Solution-based synthesis, Mechanochemical synthesis, Copper complexes, L-threonine, 1, 10-Phenanthroline}, chapternumber = {E09556} }
@article{article, author = {Vu\v{s}ak, Darko and Le\v{z}ai\'{c}, Katarina and Jurec, Jurica and \v{Z}ili\'{c}, Dijana and Prugove\v{c}ki, Biserka}, year = {2022}, pages = {18}, DOI = {https://doi.org/10.1016/j.heliyon.2022.e09556}, chapter = {E09556}, keywords = {Ternary coordination compounds, Solvatomorphs, Crystal structures, ESR spectra, Solution-based synthesis, Mechanochemical synthesis, Copper complexes, L-threonine, 1, 10-Phenanthroline}, journal = {Heliyon}, doi = {https://doi.org/10.1016/j.heliyon.2022.e09556}, volume = {8}, number = {6}, issn = {2405-8440}, title = {Solvent effects on the crystallization and structure of ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline}, keyword = {Ternary coordination compounds, Solvatomorphs, Crystal structures, ESR spectra, Solution-based synthesis, Mechanochemical synthesis, Copper complexes, L-threonine, 1, 10-Phenanthroline}, chapternumber = {E09556} }

Časopis indeksira:


  • Web of Science Core Collection (WoSCC)
    • Emerging Sources Citation Index (ESCI)
  • Scopus

Citati:

    Altmetrijski pokazatelji:


    Podijeli:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font
    CROSBI koristi kolačiće (cookies) kako bi poboljšao funkcionalnost stranice.