Pregled bibliografske jedinice broj: 1197476
Sol-gel synthesis of ceria-zirconia-based high- entropy oxides as high-promotion catalysts for the synthesis of 1,2-diketones from aldehyde
Sol-gel synthesis of ceria-zirconia-based high- entropy oxides as high-promotion catalysts for the synthesis of 1,2-diketones from aldehyde // ACS Spring 2022 Abstracts
San Diego (CA), Sjedinjene Američke Države, 2022. (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 1197476 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Sol-gel synthesis of ceria-zirconia-based high-
entropy oxides as high-promotion catalysts for
the synthesis of 1,2-diketones from aldehyde
Autori
Djerdj, Igor ; Tatar, Dalibor ; Kojčinović, Jelena ; Marković, Berislav ; Széchenyi, Aleksandar ; Miletić, Aleksandar ; Nagy, Sandor ; Ziegenheim, Szilvester ; Szenti, Imre ; Sapi, Andras ; Kukovecz, Akos ; Tang, Yushu ; Stenzel, David ; Varga, Gabor
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
ACS Spring 2022 Abstracts
/ - , 2022
Skup
ACS National Meeting and Exposition Spring 2022: Bonding Through Chemistry
Mjesto i datum
San Diego (CA), Sjedinjene Američke Države, 20.03.2022. - 24.03.2022
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
Lewis acid ; catalyst ; high entropy ; oxides ; aldehyde ; diketone
Sažetak
Efficient Lewis-acid-catalyzed direct conversion of aldehydes to 1, 2-diketones in the liquid phase was enabled by using newly designed and developed ceria–zirconia-based high-entropy oxides (HEOs) as the actual catalysts. The synergistic eàect of various cations incorporated in the same oxide structure (framework) was partially responsible for the efficiency of multicationic materials compared to the corresponding single cation oxide forms. Furthermore, a clear, linear relationship between the Lewis acidity and the catalytic activity of the HEOs was observed. Due to the developed strategy, exclusively diketone- selective, recyclable, versatile heterogeneous catalytic transformation of aldehydes can be realized under mild reaction conditions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-PZS-2019-02-2467 - Istraživanje utjecaja metalnih promotora rijetkih zemalja i stupnja uređenja na redoks svojstva sustava CeO2 - ZrO2 (SREMPOREPROCEZIS) (Đerđ, Igor, HRZZ - 2019-02) ( CroRIS)
Ustanove:
Sveučilište u Osijeku - Odjel za kemiju
Profili:
Jelena Kojčinović
(autor)
Igor Đerđ
(autor)
Berislav Marković
(autor)
Dalibor Tatar
(autor)
Aleksandar Secenji
(autor)