Pregled bibliografske jedinice broj: 1195226
Photoinduced Autonomous Nonequilibrium Operation of a Molecular Shuttle by Combined Isomerization and Proton Transfer Through a Catalytic Pathway
Photoinduced Autonomous Nonequilibrium Operation of a Molecular Shuttle by Combined Isomerization and Proton Transfer Through a Catalytic Pathway // Journal of the American Chemical Society, 144 (2022), x-xx doi:10.1021/jacs.1c13537 (međunarodna recenzija, članak, znanstveni)
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Naslov
Photoinduced Autonomous Nonequilibrium Operation
of a Molecular Shuttle by Combined Isomerization
and Proton Transfer Through a Catalytic Pathway
Autori
Nicoli, Federico* ; Curcio, Massimiliano* ; Tranfić Bakić, Marina* ; Paltrinieri, Erica ; Silvi, Serena ; Baroncini, Massimo ; Credi, Alberto
Izvornik
Journal of the American Chemical Society (0002-7863) 144
(2022);
X-xx
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
rotaxane ; molecular machine ; crown ether ; mechanical bond ; E/Z isomer acidity
Sažetak
We describe a [2]rotaxane whose recognition sites for the ring are a dibenzylammonium moiety, endowed with acidic and H-bonding donor properties, and an imidazolium center bearing a photoactive phenylazo substituent. Light irradiation of this compound triggers a network of E/Z isomerization and proton transfer reactions that enable autonomous and reversible ring shuttling away from equilibrium.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
- Nature Index