Pregled bibliografske jedinice broj: 1187277
One-Step Synthesis of 5a,11a-Janusene Imide Employing 2,3-Dibromo-N-methylmaleimide as Acetylene Equivalent
One-Step Synthesis of 5a,11a-Janusene Imide Employing 2,3-Dibromo-N-methylmaleimide as Acetylene Equivalent // Chemistry Proceedings, 2021, 3(1)
online: MDPI Books, 2020. 87, 6 doi:10.3390/ecsoc-24-08426 (predavanje, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)
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Naslov
One-Step Synthesis of 5a,11a-Janusene Imide
Employing 2,3-Dibromo-N-methylmaleimide as
Acetylene Equivalent
Autori
Štrbac, Petar ; Margetić, Davor
Vrsta, podvrsta i kategorija rada
Radovi u zbornicima skupova, cjeloviti rad (in extenso), znanstveni
Izvornik
Chemistry Proceedings, 2021, 3(1)
/ - : MDPI Books, 2020
Skup
24th International Electronic Conference on Synthetic Organic Chemistry
Mjesto i datum
Online, 15.11.2020. - 15.12.2020
Vrsta sudjelovanja
Predavanje
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
cycloaddition ; anthracene ; microwave assisted organic reactions ; Diels-Alder reaction ; cycloreversion
Sažetak
Synthesis of janusene (5, 5a, 6, 11, 11a, 12- hexahydro-5, 12:6, 11-di-o-benzenonaphthacene) requires several reaction steps, starting from anthracene. In this account, a one-pot, three-step synthesis of janusene N-methyl-5a, 11a- dicarboximide employing 2, 3-dibromo-N- methylmaleimide as an acetylene equivalent is described. This thermal reaction is a simple synthetic procedure in comparison to sequential- multi step [4+2] cycloaddition routes. Here, 2, 3- dibromo-N-methylmaleimide acts effectively as a ‘molecular glue’, bridging two anthracene molecules together.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
