Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1144538

From icebergs to geysers: the story behind hydrophobic effect


Usenik, Andrea; Leko, Katarina; Hanževački, Marko; Pičuljan, Katarina; Petrović Peroković, Vesna; Car, Željka; Požar, Josip
From icebergs to geysers: the story behind hydrophobic effect // 5. Simpozij studenata doktorskih studija PMF-a 2021 : knjiga sažetaka / Barišić, Dajana (ur.).
Zagreb: Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu, 2021. str. 93-94 (predavanje, nije recenziran, sažetak, znanstveni)


CROSBI ID: 1144538 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
From icebergs to geysers: the story behind hydrophobic effect

Autori
Usenik, Andrea ; Leko, Katarina ; Hanževački, Marko ; Pičuljan, Katarina ; Petrović Peroković, Vesna ; Car, Željka ; Požar, Josip

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
5. Simpozij studenata doktorskih studija PMF-a 2021 : knjiga sažetaka / Barišić, Dajana - Zagreb : Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu, 2021, 93-94

ISBN
978-953-6076-90-1

Skup
5. Simpozij studenata doktorskih studija PMF-a = 5th Faculty of Science PhD Student Symposium

Mjesto i datum
Zagreb, Hrvatska, 24.04.2021. - 25.04.2021

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Nije recenziran

Ključne riječi
hydrophobic effect ; solvophobic effect ; inclusion complex ; complexation thermodynamics ; cyclodextrins ; cucurbit[7]uril ; mannoconjugates

Sažetak
The temperature and solvent effect on the complexation of various guests (Figure 1) with α-, β- and γ-cyclodextrin and cucurbit[7]uril was explored experimentally and by means of molecular dynamics simulations. The stability constants of all investigated complexes were by far the highest with cucurbit[7]uril in water. A pronounced temperature dependence of ΔrH° and ΔrS°, resulting in almost complete enthalpy-entropy compensation was observed for most explored host-guest systems. For those systems complexation thermodynamics was in line with the classical rationale of the hydrophobic effect at lower temperatures, and the non-classical explanation at higher ones. The optimized inclusion complex structures corresponded to those deduced by means of NMR spectroscopy and the experimentally obtained and calculated ΔrG° were in very good agreement.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-IP-2019-04-9560 - Koordinacijske reakcije makrocikličkih liganada u otopini (MacroSol) (Tomišić, Vladislav, HRZZ - 2019-04) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Poveznice na cjeloviti tekst rada:

www.pmf.unizg.hr

Citiraj ovu publikaciju:

Usenik, Andrea; Leko, Katarina; Hanževački, Marko; Pičuljan, Katarina; Petrović Peroković, Vesna; Car, Željka; Požar, Josip
From icebergs to geysers: the story behind hydrophobic effect // 5. Simpozij studenata doktorskih studija PMF-a 2021 : knjiga sažetaka / Barišić, Dajana (ur.).
Zagreb: Prirodoslovno-matematički fakultet Sveučilišta u Zagrebu, 2021. str. 93-94 (predavanje, nije recenziran, sažetak, znanstveni)
Usenik, A., Leko, K., Hanževački, M., Pičuljan, K., Petrović Peroković, V., Car, Ž. & Požar, J. (2021) From icebergs to geysers: the story behind hydrophobic effect. U: Barišić, D. (ur.)5. Simpozij studenata doktorskih studija PMF-a 2021 : knjiga sažetaka.
@article{article, author = {Usenik, Andrea and Leko, Katarina and Han\v{z}eva\v{c}ki, Marko and Pi\v{c}uljan, Katarina and Petrovi\'{c} Perokovi\'{c}, Vesna and Car, \v{Z}eljka and Po\v{z}ar, Josip}, editor = {Bari\v{s}i\'{c}, D.}, year = {2021}, pages = {93-94}, keywords = {hydrophobic effect, solvophobic effect, inclusion complex, complexation thermodynamics, cyclodextrins, cucurbit[7]uril, mannoconjugates}, isbn = {978-953-6076-90-1}, title = {From icebergs to geysers: the story behind hydrophobic effect}, keyword = {hydrophobic effect, solvophobic effect, inclusion complex, complexation thermodynamics, cyclodextrins, cucurbit[7]uril, mannoconjugates}, publisher = {Prirodoslovno-matemati\v{c}ki fakultet Sveu\v{c}ili\v{s}ta u Zagrebu}, publisherplace = {Zagreb, Hrvatska} }
@article{article, author = {Usenik, Andrea and Leko, Katarina and Han\v{z}eva\v{c}ki, Marko and Pi\v{c}uljan, Katarina and Petrovi\'{c} Perokovi\'{c}, Vesna and Car, \v{Z}eljka and Po\v{z}ar, Josip}, editor = {Bari\v{s}i\'{c}, D.}, year = {2021}, pages = {93-94}, keywords = {hydrophobic effect, solvophobic effect, inclusion complex, complexation thermodynamics, cyclodextrins, cucurbit[7]uril, mannoconjugates}, isbn = {978-953-6076-90-1}, title = {From icebergs to geysers: the story behind hydrophobic effect}, keyword = {hydrophobic effect, solvophobic effect, inclusion complex, complexation thermodynamics, cyclodextrins, cucurbit[7]uril, mannoconjugates}, publisher = {Prirodoslovno-matemati\v{c}ki fakultet Sveu\v{c}ili\v{s}ta u Zagrebu}, publisherplace = {Zagreb, Hrvatska} }




Contrast
Increase Font
Decrease Font
Dyslexic Font