Naslov
From molecular electrostatic potential surfaces to practical avenues for directed assembly of organic and metal-containing crystalline materials

Autori
Aakeröy, Christer ; Đaković, Marijana

Vrsta, podvrsta i kategorija rada
Poglavlja u knjigama, znanstveni

Knjiga
Hot topics in crystal engineering

Urednik/ci
Risannen, Kari

Izdavač
Elsevier

Grad
Amsterdam

Godina
2021

Raspon stranica
231-279

ISBN
978-0-12-818192-8

Ključne riječi
crystal engineering, hydrogen bonds, halogen bonds, MEP, supramolecular synthetic guidelines

Sažetak
From discrete and dispersed, to condensed and organized, intermolecular interactions provide the links between molecular structure and bulk properties of crystalline materials. They also hold the key to effective bottom-up approaches toward design and synthesis of both single- component and multicomponent organic solids, as well as of coordination compounds with desirable structural features. The deceptively simple act of molecular recognition creates the means whereby different discrete chemical components recognize, bind, and aggregate, and such events are controlled by a delicate balance and competition between intermolecular forces that inhabit a broad range of energy scales. The primary challenge hampering reliable synthesis of materials with precise structural metrics and desired chemical composition is the shortage of transferable guidelines for preplanned crystal engineering based on noncovalent interactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA