Naslov
Coordination polymers of the {;MoO2 2+};-dihydrazone type as structurally and topologically versatile systems

Autori
Topić, Edi ; Rubčić, Mirta ; Vrdoljak, Višnja

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research 2021 : Book of Abstracts / Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina - Zagreb : Institut Ruđer Bošković, 2021, 77-77

ISBN
978-953-7941-35-2

Skup
Solid-State Science & Research 2021 (SCIRES2021)

Mjesto i datum
Zagreb, Hrvatska, 10.06.2021. - 11.06.2021

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
molybdenum(VI) complexes ; dihydrazone ; coordination polymers

Sažetak
Dioxomolybdenum(VI) complexes based on dihydrazone scaffolds have proved well their coordination and supramolecular prospects for the design of materials ranging from discrete multinuclear complexes to polyoxometalates.1 In contrast to their rigid benzhydrazones and carbohydrazone congeners, alkyl (di)hydrazones offer entirely new scenarios when considering materials framework topology. As we show, the extreme topological richness can be achieved by combining flexible alkyl (di)hydrazones with rigid bis(pyridyl) linkers, while relying on the coordinatively predictable MoO22+ core. A detailed structural analysis unveils that the geometrical features and topology of the polymers are dictated by the conformational flexibility of the alkyl chain of the ligand, as well as hydrogen-bonding propensities of peripheral functional groups.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA