Naslov
Mechanochemical Synthesis of Novel Mg- and Ca- Containing Bimetallic Amidoboranes

Autori
Milanović, Igor ; Biliškov, Nikola ; Užarević, Krunoslav ; Lukin, Stipe ; Halasz, Ivan

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid State Science and Research 2021 : Book of Abstracts and Programme / Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina - Zagreb : Institut Ruđer Bošković, 2021, 50-50

ISBN
978-953-7941-35-2

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 10.06.2021. - 11.06.2021

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Mechanochemistry ; In-situ monitoring ; Amidoboranes ; Hydrogen storage

Sažetak
Mechanochemistry can be very useful for synthesis of bimetallic amidoboranes - very prominent materials for hydrogen storage. By using the mechanical ball milling technique, solventless solid state reaction between ammonia borane (NH3BH3), alkali metal hydrides (NaH, LiH) and alkaline earth metal hydrides (CaH2 and MgH2) is absolutely possible [1, 2]. Exclusively hydrogen and bimetallic amidoboranes are obtained as final products. Here we report several examples of successful synthesis - Na2Mg(NH2BH3)4, Li2Mg(NH2BH3)4, Na2Ca(NH2BH3)4 and Li2Ca(NH2BH3)4 – all prepared and characterised by our group.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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