Pregled bibliografske jedinice broj: 1131821
Fine-tuning of mechanical flexibility of cadmium(II) halide crystals via ligand replacement
Fine-tuning of mechanical flexibility of cadmium(II) halide crystals via ligand replacement // Solid-State Science & Research 2021 : Book of Abstracts / Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina (ur.).
Zagreb: Institut Ruđer Bošković, 2021. str. 75-75 (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 1131821 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Fine-tuning of mechanical flexibility of cadmium(II)
halide crystals via ligand replacement
Autori
Čolakić, Lea ; Pisačić, Mateja ; Đaković, Marijana
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Solid-State Science & Research 2021 : Book of Abstracts
/ Biliškov, Nikola ; Brekalo, Ivana ; Martinez, Valentina - Zagreb : Institut Ruđer Bošković, 2021, 75-75
ISBN
978-953-7941-35-2
Skup
Solid-State Science & Research 2021 (SCIRES2021)
Mjesto i datum
Zagreb, Hrvatska, 10.06.2021. - 11.06.2021
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
coordination polymers, cadmium(II), mechanical response, elastic
Sažetak
Molecular crystals are excellent candidates for designing a wide range of functional materials due to their arranged internal structure. However, the brittleness and stiffness of the crystals have so far proved to be a limiting factor in their practical implementation. In recent years, there has been an increasing number of molecular crystals that show a flexible response when mechanical force is applied to them, [1, 2] but also it has been shown that the degree of mechanical response can be controlled by introducing small structural changes. [3, 4] In order to clarify the influence of different structural parameters on mechanical flexibility, we present a new family of coordination cadmium(II) polymers with 2, 6-diiodopyrazine, which also show a flexible response to external mechanical force. The molecular and crystal structure were determined and the structural characteristics of the prepared compounds were correlated with the extent of mechanical response. [1] C. M Reddy, G. R Krishna, S. Ghosh, CrystEngComm 12 (2010) 2296. [2] A. Worthy, A. Grosjean, M. C. Pfrunder, Y. Xu, C. Yan, G. Edwards, J. K. Clegg, J. C. McMurtrie, Nat. Chem. 10 (2018) 65. [3] M. Đaković, M. Borovina, M. Pisačić, C.B. Aakeröy, Ž.Soldin, B.-M. Kukovec, I. Kodrin, Angew. Chem. Int. Ed. 57 (2018) 14801. [4] M. Pisačić, I. Biljan, I. Kodrin, N. Popov, Ž. Soldin, M. Đaković, Chem.Mater. 33 (2021) 3660.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
--IP-2019-04-1242 - Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom (FlexibleCrystals) (Đaković, Marijana) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
